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The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites. / Штарев , Дмитрий Сергеевич; Баланов , Михаил ; Майер, А; Герасименко, А; Кеворкянц, Руслан Эдуардович; Жаровов, Дмитрий Анатольевич; Буланин, Кирилл Михайлович; Рудакова, Аида Витальевна; Чаплыгина, Д; Селиванов, Никита Иванович; Емелин, Алексей Владимирович.

In: Journal of Materials Chemistry C, Vol. 12, No. 1, 01.01.2024, p. 262-275.

Research output: Contribution to journal › Article › peer-review

Harvard

Штарев , ДС, Баланов , М, Майер, А, Герасименко, А, Кеворкянц, РЭ, Жаровов, ДА, Буланин, КМ, Рудакова, АВ, Чаплыгина, Д, Селиванов, НИ & Емелин, АВ 2024, 'The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites', Journal of Materials Chemistry C, vol. 12, no. 1, pp. 262-275. https://doi.org/10.1039/d3tc02767h

APA

Штарев , Д. С., Баланов , М., Майер, А., Герасименко, А., Кеворкянц, Р. Э., Жаровов, Д. А., Буланин, К. М., Рудакова, А. В., Чаплыгина, Д., Селиванов, Н. И., & Емелин, А. В. (2024). The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites. Journal of Materials Chemistry C, 12(1), 262-275. https://doi.org/10.1039/d3tc02767h

Vancouver

Штарев ДС, Баланов М, Майер А, Герасименко А, Кеворкянц РЭ, Жаровов ДА et al. The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites. Journal of Materials Chemistry C. 2024 Jan 1;12(1):262-275. https://doi.org/10.1039/d3tc02767h

Author

Штарев , Дмитрий Сергеевич ; Баланов , Михаил ; Майер, А ; Герасименко, А ; Кеворкянц, Руслан Эдуардович ; Жаровов, Дмитрий Анатольевич ; Буланин, Кирилл Михайлович ; Рудакова, Аида Витальевна ; Чаплыгина, Д ; Селиванов, Никита Иванович ; Емелин, Алексей Владимирович. / The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites. In: Journal of Materials Chemistry C. 2024 ; Vol. 12, No. 1. pp. 262-275.

BibTeX

@article{b093a7b6014a41c08d4e7de396a02e59,
title = "The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites",
abstract = "The present work reports on experimental structures, optoelectronic, and luminescence properties of the series of low-dimensional hybrid organic-inorganic (1,5-Pentanediamine)PbX4 (X=Cl, Br, I) perovskites. Single-crystal XRD data revealed that the chloride and bromide compounds form quasi 2D perovskite-like structures, whereas the iodide is quasi 1D compound. In accordance with experiment, DFT modeling predicts that the chloride and bromide are direct bandgap semiconductors. In contrast, the iodide is an indirect bandgap semiconductor. Experimentally and theoretically established bandgaps widths of the perovskites follow the same trend. Finally, luminescent properties of the perovskites were investigated. The study shows that the halogen anionsdetermine the degree of disorder of the perovskite crystal lattices and degree of distortion of PbX6 octahedra therein. Both structural phenomena affect dimensionality, optoelectronic, and luminescent properties of the studied perovskites.",
author = "Штарев, {Дмитрий Сергеевич} and Михаил Баланов and А Майер and А Герасименко and Кеворкянц, {Руслан Эдуардович} and Жаровов, {Дмитрий Анатольевич} and Буланин, {Кирилл Михайлович} and Рудакова, {Аида Витальевна} and Д Чаплыгина and Селиванов, {Никита Иванович} and Емелин, {Алексей Владимирович}",
year = "2024",
month = jan,
day = "1",
doi = "10.1039/d3tc02767h",
language = "English",
volume = "12",
pages = "262--275",
journal = "Journal of Materials Chemistry C",
issn = "2050-7526",
publisher = "Royal Society of Chemistry",
number = "1",

}

RIS

TY - JOUR

T1 - The effect of the halogen on the structural, optoelectronic, and luminescent properties of hybrid (1,5-pentanediamine)PbX4 (X = Cl, Br, I) perovskites

AU - Штарев , Дмитрий Сергеевич

AU - Баланов , Михаил

AU - Майер, А

AU - Герасименко, А

AU - Кеворкянц, Руслан Эдуардович

AU - Жаровов, Дмитрий Анатольевич

AU - Буланин, Кирилл Михайлович

AU - Рудакова, Аида Витальевна

AU - Чаплыгина, Д

AU - Селиванов, Никита Иванович

AU - Емелин, Алексей Владимирович

PY - 2024/1/1

Y1 - 2024/1/1

N2 - The present work reports on experimental structures, optoelectronic, and luminescence properties of the series of low-dimensional hybrid organic-inorganic (1,5-Pentanediamine)PbX4 (X=Cl, Br, I) perovskites. Single-crystal XRD data revealed that the chloride and bromide compounds form quasi 2D perovskite-like structures, whereas the iodide is quasi 1D compound. In accordance with experiment, DFT modeling predicts that the chloride and bromide are direct bandgap semiconductors. In contrast, the iodide is an indirect bandgap semiconductor. Experimentally and theoretically established bandgaps widths of the perovskites follow the same trend. Finally, luminescent properties of the perovskites were investigated. The study shows that the halogen anionsdetermine the degree of disorder of the perovskite crystal lattices and degree of distortion of PbX6 octahedra therein. Both structural phenomena affect dimensionality, optoelectronic, and luminescent properties of the studied perovskites.

AB - The present work reports on experimental structures, optoelectronic, and luminescence properties of the series of low-dimensional hybrid organic-inorganic (1,5-Pentanediamine)PbX4 (X=Cl, Br, I) perovskites. Single-crystal XRD data revealed that the chloride and bromide compounds form quasi 2D perovskite-like structures, whereas the iodide is quasi 1D compound. In accordance with experiment, DFT modeling predicts that the chloride and bromide are direct bandgap semiconductors. In contrast, the iodide is an indirect bandgap semiconductor. Experimentally and theoretically established bandgaps widths of the perovskites follow the same trend. Finally, luminescent properties of the perovskites were investigated. The study shows that the halogen anionsdetermine the degree of disorder of the perovskite crystal lattices and degree of distortion of PbX6 octahedra therein. Both structural phenomena affect dimensionality, optoelectronic, and luminescent properties of the studied perovskites.

UR - https://pubs.rsc.org/en/content/articlelanding/2023/tc/d3tc02767h/unauth

UR - https://www.mendeley.com/catalogue/8c3c8c2f-48d9-3410-8a0e-1ee8adca1753/

U2 - 10.1039/d3tc02767h

DO - 10.1039/d3tc02767h

M3 - Article

VL - 12

SP - 262

EP - 275

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

SN - 2050-7526

IS - 1

ER -

ID: 114414799