The effect of a finite number of monomers available for aggregation at nucleation and micellization in a fixed volume

Standard

The effect of a finite number of monomers available for aggregation at nucleation and micellization in a fixed volume. / Shchekin, A. K.; Koga, K.; Volkov, N. A.

In: The Journal of Chemical Physics, Vol. 151, No. 24, 244903, 28.12.2019.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{176c3ab82de0443299cdd582d7432596,

title = "The effect of a finite number of monomers available for aggregation at nucleation and micellization in a fixed volume",

abstract = "The expressions for the minimal work of aggregate formation as a function of the aggregation number and monomer concentration for a system with a limited number of monomers and a fixed volume have additional terms in comparison with a bulk metastable phase. The role of these terms has been analyzed in the case of droplet homogeneous nucleation and micellization in a nonionic surfactant solution. The appearance of the potential well and direct and reversal aggregation barriers in such systems and their dependence on the system parameters and monomer concentration have been considered and compared.",

keywords = "THERMODYNAMIC CHARACTERISTICS, KINETIC DESCRIPTION, HOMOGENEOUS NUCLEATION, FAST RELAXATION, MICELLES, DROPLET, BUBBLES, SIZE, CONDENSATION, DIFFUSION",

author = "Shchekin, {A. K.} and K. Koga and Volkov, {N. A.}",

year = "2019",

month = dec,

day = "28",

doi = "10.1063/1.5129160",

language = "English",

volume = "151",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "24",

}

RIS

TY - JOUR

T1 - The effect of a finite number of monomers available for aggregation at nucleation and micellization in a fixed volume

AU - Shchekin, A. K.

AU - Koga, K.

AU - Volkov, N. A.

PY - 2019/12/28

Y1 - 2019/12/28

N2 - The expressions for the minimal work of aggregate formation as a function of the aggregation number and monomer concentration for a system with a limited number of monomers and a fixed volume have additional terms in comparison with a bulk metastable phase. The role of these terms has been analyzed in the case of droplet homogeneous nucleation and micellization in a nonionic surfactant solution. The appearance of the potential well and direct and reversal aggregation barriers in such systems and their dependence on the system parameters and monomer concentration have been considered and compared.

AB - The expressions for the minimal work of aggregate formation as a function of the aggregation number and monomer concentration for a system with a limited number of monomers and a fixed volume have additional terms in comparison with a bulk metastable phase. The role of these terms has been analyzed in the case of droplet homogeneous nucleation and micellization in a nonionic surfactant solution. The appearance of the potential well and direct and reversal aggregation barriers in such systems and their dependence on the system parameters and monomer concentration have been considered and compared.

KW - THERMODYNAMIC CHARACTERISTICS

KW - KINETIC DESCRIPTION

KW - HOMOGENEOUS NUCLEATION

KW - FAST RELAXATION

KW - MICELLES

KW - DROPLET

KW - BUBBLES

KW - SIZE

KW - CONDENSATION

KW - DIFFUSION

UR - http://www.scopus.com/inward/record.url?scp=85077356929&partnerID=8YFLogxK

U2 - 10.1063/1.5129160

DO - 10.1063/1.5129160

M3 - Article

C2 - 31893896

AN - SCOPUS:85077356929

VL - 151

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 24

M1 - 244903

ER -

ID: 50489304