The condition of internal mechanical equilibrium of a curved surface layer is derived, and its application to practically important cases of incomplete formation of the surface layer (as is sometimes the case, for example, in thin films) is considered. The notion of a local disjoining pressure is introduced, and the equilibrium condition for a variable-thickness thin film is obtained; this condition is valid both in the absence and in the presence of external fields. The cases of a wedge-shaped film, cylindrical film, spherical film, and transition zone of a wetting film are analyzed.

Translated title of the contributionУСЛОВИЕ МЕХАНИЧЕСКОГО РАВНОВЕСИЯ НА ПОВЕРХНОСТИ НЕОДНОРОДНОЙ ТОНКОЙ ПЛЕНКИ
Original languageEnglish
Pages (from-to)205-212
Number of pages8
JournalColloid Journal
Volume67
Issue number2
DOIs
StatePublished - 1 Mar 2005

    Scopus subject areas

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

ID: 5013481