Research output: Contribution to journal › Article › peer-review
The Composition and Magnetic Structure of Fe3O4/γ-Fe2O3 Core–Shell Nanocomposites at 300 and 80 K : Mössbauer Study (Part I). / Kamzin, A. S.; Obaidat, I. M.; Valliulin, A. A.; Semenov, V. G.; Al-Omari, I. A.
In: Physics of the Solid State, Vol. 62, No. 10, 01.10.2020, p. 1933-1943.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The Composition and Magnetic Structure of Fe3O4/γ-Fe2O3 Core–Shell Nanocomposites at 300 and 80 K
T2 - Mössbauer Study (Part I)
AU - Kamzin, A. S.
AU - Obaidat, I. M.
AU - Valliulin, A. A.
AU - Semenov, V. G.
AU - Al-Omari, I. A.
N1 - Funding Information: I.M. Obaidat and I.A. Al-Omari are grateful to the financial support of the UAEU Advanced Research Program (UPAR), grant No. 31S241. Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - Abstract: The magnetic structure and the composition of Fe3O4/γ-Fe2O3 nanoparticles are studied at 300 and 80 K with Mössbauer spectroscopy. We found that the Fe3O4/γ-Fe2O3 particles are a core–shell nanocomposite (NC), in which magnetite Fe3O4 is covered with a maghemite shell (γ-Fe2O3). We showed that the thickness of the maghemite shell (γ-Fe2O3) depends on synthesis technology. We found that a layer, whose magnetic structure differs from that of the inner part of the shell (γ-Fe2O3), is formed on the surface of the maghemite shell (γ-Fe2O3) in the Fe3O4/γ-Fe2O3 NC. An intermediate layer is formed in the spin-glass state between the core and the shell. The data on structure of core–shell nanocomposites open up prospects to explain the properties of such particles, which are of great interest to use in various fields, including biomedicine.
AB - Abstract: The magnetic structure and the composition of Fe3O4/γ-Fe2O3 nanoparticles are studied at 300 and 80 K with Mössbauer spectroscopy. We found that the Fe3O4/γ-Fe2O3 particles are a core–shell nanocomposite (NC), in which magnetite Fe3O4 is covered with a maghemite shell (γ-Fe2O3). We showed that the thickness of the maghemite shell (γ-Fe2O3) depends on synthesis technology. We found that a layer, whose magnetic structure differs from that of the inner part of the shell (γ-Fe2O3), is formed on the surface of the maghemite shell (γ-Fe2O3) in the Fe3O4/γ-Fe2O3 NC. An intermediate layer is formed in the spin-glass state between the core and the shell. The data on structure of core–shell nanocomposites open up prospects to explain the properties of such particles, which are of great interest to use in various fields, including biomedicine.
KW - biomedicine
KW - core–shell magnetic composites
KW - magnetic nanocomposites
KW - magnetic nanoparticles
KW - IRON-OXIDE NANOPARTICLES
KW - SYSTEM
KW - core-shell magnetic composites
KW - SIZE
KW - NANOCRYSTALS
KW - TEMPERATURE OXIDATION
KW - PARAMETERS
KW - GAMMA-FE2O3
KW - TRANSITION
KW - MAGHEMITE NANOPARTICLES
UR - http://www.scopus.com/inward/record.url?scp=85092321370&partnerID=8YFLogxK
U2 - 10.1134/S1063783420100157
DO - 10.1134/S1063783420100157
M3 - Article
AN - SCOPUS:85092321370
VL - 62
SP - 1933
EP - 1943
JO - Physics of the Solid State
JF - Physics of the Solid State
SN - 1063-7834
IS - 10
ER -
ID: 70756157