Standard

Tellurites of Hexavalent Uranium: First Observation of Polymerized (UO4)2–Tetraoxido Cores. / Zadoya, A.I.; Siidra, O.I.; Bubnova, R.S.; Nazarchuk, E.V.; Bocharov, S.N.

In: European Journal of Inorganic Chemistry, No. 25, 2016, p. 4083-4089.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Author

BibTeX

@article{b418ddeb4b1641fc8d4e075eb9fb47f9,
title = "Tellurites of Hexavalent Uranium: First Observation of Polymerized (UO4)2–Tetraoxido Cores",
abstract = "wo novel Ca2(UO3)(TeO3)2(1) and K2(UO2)2O2(TeO3) (2) uranyl tellurites were obtained from telluric acid, used as a starting reagent for both compounds. In 1, the tetraoxido core is coordinated by TeO3groups and UO4squares polymerize into [UO3] chains. The tetraoxido core coordination modes in compound 1 are unique. New layered⋡ 2[(UO2)2(TeO3)O2]2–topology is observed for 2. Both of the compounds were studied by the means of high-temperature X-ray diffraction. The thermal decomposition of 1 and 2 is different and leads to formation of uranate compounds.",
author = "A.I. Zadoya and O.I. Siidra and R.S. Bubnova and E.V. Nazarchuk and S.N. Bocharov",
year = "2016",
doi = "10.1002/ejic.201600624",
language = "English",
pages = "4083--4089",
journal = "Berichte der deutschen chemischen Gesellschaft",
issn = "0365-9496",
publisher = "Wiley-Blackwell",
number = "25",

}

RIS

TY - JOUR

T1 - Tellurites of Hexavalent Uranium: First Observation of Polymerized (UO4)2–Tetraoxido Cores

AU - Zadoya, A.I.

AU - Siidra, O.I.

AU - Bubnova, R.S.

AU - Nazarchuk, E.V.

AU - Bocharov, S.N.

PY - 2016

Y1 - 2016

N2 - wo novel Ca2(UO3)(TeO3)2(1) and K2(UO2)2O2(TeO3) (2) uranyl tellurites were obtained from telluric acid, used as a starting reagent for both compounds. In 1, the tetraoxido core is coordinated by TeO3groups and UO4squares polymerize into [UO3] chains. The tetraoxido core coordination modes in compound 1 are unique. New layered⋡ 2[(UO2)2(TeO3)O2]2–topology is observed for 2. Both of the compounds were studied by the means of high-temperature X-ray diffraction. The thermal decomposition of 1 and 2 is different and leads to formation of uranate compounds.

AB - wo novel Ca2(UO3)(TeO3)2(1) and K2(UO2)2O2(TeO3) (2) uranyl tellurites were obtained from telluric acid, used as a starting reagent for both compounds. In 1, the tetraoxido core is coordinated by TeO3groups and UO4squares polymerize into [UO3] chains. The tetraoxido core coordination modes in compound 1 are unique. New layered⋡ 2[(UO2)2(TeO3)O2]2–topology is observed for 2. Both of the compounds were studied by the means of high-temperature X-ray diffraction. The thermal decomposition of 1 and 2 is different and leads to formation of uranate compounds.

U2 - 10.1002/ejic.201600624

DO - 10.1002/ejic.201600624

M3 - Article

SP - 4083

EP - 4089

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 25

ER -

ID: 7607328