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Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters. / Miroslavov, A.; Polotskii, Y.; Gurzhiy, V.; Ivanov, A.; Lumpov, A.; Tyupina, M.; Sidorenko, G.; Tolstoy, P.; Maltsev, D.; Suglobov, D.

In: Inorganic Chemistry, Vol. 53, 2014, p. 7861-7869.

Research output: Contribution to journal › Article

Harvard

Miroslavov, A, Polotskii, Y, Gurzhiy, V, Ivanov, A, Lumpov, A, Tyupina, M, Sidorenko, G, Tolstoy, P, Maltsev, D & Suglobov, D 2014, 'Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters', Inorganic Chemistry, vol. 53, pp. 7861-7869.

APA

Miroslavov, A., Polotskii, Y., Gurzhiy, V., Ivanov, A., Lumpov, A., Tyupina, M., Sidorenko, G., Tolstoy, P., Maltsev, D., & Suglobov, D. (2014). Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters. Inorganic Chemistry, 53, 7861-7869.

Vancouver

Miroslavov A, Polotskii Y, Gurzhiy V, Ivanov A, Lumpov A, Tyupina M et al. Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters. Inorganic Chemistry. 2014;53:7861-7869.

Author

Miroslavov, A. ; Polotskii, Y. ; Gurzhiy, V. ; Ivanov, A. ; Lumpov, A. ; Tyupina, M. ; Sidorenko, G. ; Tolstoy, P. ; Maltsev, D. ; Suglobov, D. / Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters. In: Inorganic Chemistry. 2014 ; Vol. 53. pp. 7861-7869.

BibTeX

@article{5d0578c45ee34e5bb0a773272184afb6,
title = "Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters",
abstract = "Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11- isocyanoundecanoate, [M(CO)5(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)5(CN(CH2)10COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, 1H NMR, and 13C{1H} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)6]+. It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable under these co",
author = "A. Miroslavov and Y. Polotskii and V. Gurzhiy and A. Ivanov and A. Lumpov and M. Tyupina and G. Sidorenko and P. Tolstoy and D. Maltsev and D. Suglobov",
year = "2014",
language = "English",
volume = "53",
pages = "7861--7869",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

RIS

TY - JOUR

T1 - Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω-Isocyanocarboxylic Acid Esters

AU - Miroslavov, A.

AU - Polotskii, Y.

AU - Gurzhiy, V.

AU - Ivanov, A.

AU - Lumpov, A.

AU - Tyupina, M.

AU - Sidorenko, G.

AU - Tolstoy, P.

AU - Maltsev, D.

AU - Suglobov, D.

PY - 2014

Y1 - 2014

N2 - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11- isocyanoundecanoate, [M(CO)5(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)5(CN(CH2)10COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, 1H NMR, and 13C{1H} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)6]+. It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable under these co

AB - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11- isocyanoundecanoate, [M(CO)5(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)5(CN(CH2)10COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, 1H NMR, and 13C{1H} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)6]+. It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable under these co

M3 - Article

VL - 53

SP - 7861

EP - 7869

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -

ID: 5744130