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Synthetic Studies towards CH-Diazomethane Sulfonamides : a Novel Type of Diazo Reagents. / Bubyrev, Andrey; Dar'in, Dmitry; Kantin, Grigory; Krasavin, Mikhail.

In: European Journal of Organic Chemistry, Vol. 2020, No. 27, 23.07.2020, p. 4112-4115.

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Bubyrev, Andrey ; Dar'in, Dmitry ; Kantin, Grigory ; Krasavin, Mikhail. / Synthetic Studies towards CH-Diazomethane Sulfonamides : a Novel Type of Diazo Reagents. In: European Journal of Organic Chemistry. 2020 ; Vol. 2020, No. 27. pp. 4112-4115.

BibTeX

@article{7d8c6e45c6ce480ebbe82267d5097a45,
title = "Synthetic Studies towards CH-Diazomethane Sulfonamides: a Novel Type of Diazo Reagents",
abstract = "Preparation of CH-diazomethane sulfonamides has been developed for the first time. Their utility as a new type of diazo reagents was showcased in cycloaddition reactions with electron-deficient alkynes and beta-nitro styrenes which delivered medicinally important pyrazole-3-sulfonamides in good to excellent yields.",
keywords = "SAFE diazo transfer, Deacetylation, Diazomethane sulfonamides, Cycloaddition, Alkynes, ALPHA-DIAZOPHOSPHONIC ACIDS",
author = "Andrey Bubyrev and Dmitry Dar'in and Grigory Kantin and Mikhail Krasavin",
year = "2020",
month = jul,
day = "23",
doi = "10.1002/ejoc.202000446",
language = "English",
volume = "2020",
pages = "4112--4115",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-Blackwell",
number = "27",

}

RIS

TY - JOUR

T1 - Synthetic Studies towards CH-Diazomethane Sulfonamides

T2 - a Novel Type of Diazo Reagents

AU - Bubyrev, Andrey

AU - Dar'in, Dmitry

AU - Kantin, Grigory

AU - Krasavin, Mikhail

PY - 2020/7/23

Y1 - 2020/7/23

N2 - Preparation of CH-diazomethane sulfonamides has been developed for the first time. Their utility as a new type of diazo reagents was showcased in cycloaddition reactions with electron-deficient alkynes and beta-nitro styrenes which delivered medicinally important pyrazole-3-sulfonamides in good to excellent yields.

AB - Preparation of CH-diazomethane sulfonamides has been developed for the first time. Their utility as a new type of diazo reagents was showcased in cycloaddition reactions with electron-deficient alkynes and beta-nitro styrenes which delivered medicinally important pyrazole-3-sulfonamides in good to excellent yields.

KW - SAFE diazo transfer

KW - Deacetylation

KW - Diazomethane sulfonamides

KW - Cycloaddition

KW - Alkynes

KW - ALPHA-DIAZOPHOSPHONIC ACIDS

UR - http://www.scopus.com/inward/record.url?scp=85085054974&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/e1772450-0747-31f4-9d75-e46c4ec6c43c/

U2 - 10.1002/ejoc.202000446

DO - 10.1002/ejoc.202000446

M3 - Article

VL - 2020

SP - 4112

EP - 4115

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 27

ER -

ID: 53690532