Research output: Contribution to journal › Article
Synthesis, vaporization and thermodynamics of ceramic powders based on the Y2O3-ZrO2-HfO2 system. / Sevastyanov, V.G.; Simonenko, E.P.; Simonenko, N.P.; Stolyarova, V.L.; Lopatin, S.I.; Kuznetsov, N.T.
In: Materials Chemistry and Physics, Vol. 153, 2015, p. 78-87.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis, vaporization and thermodynamics of ceramic powders based on the Y2O3-ZrO2-HfO2 system
AU - Sevastyanov, V.G.
AU - Simonenko, E.P.
AU - Simonenko, N.P.
AU - Stolyarova, V.L.
AU - Lopatin, S.I.
AU - Kuznetsov, N.T.
PY - 2015
Y1 - 2015
N2 - © 2014 Elsevier B.V. All rights reserved.Nano-particles of refractory oxides based on the Y2O3-ZrO2-HfO2 system (cubic phase) were synthesized using the glycol-citrate method. The dependence of the morphology and fineness of the powder obtained on the heat treatment conditions was considered. Vaporization processes and thermodynamic properties of ceramic powder in the Y2O3-ZrO2-HfO2 system were studied by the Knudsen effusion mass spectrometric method in the temperature range 2700-2925 K. It was found that at the temperature (2773 ± 40) K the ceramic powder containing Y2O3:ZrO2:HfO2 as 0.15:0.60:0.25 mol fractions underwent a congruent sublimation. The phenomenon observed was confirmed during ten hours vaporization under conditions intermediate to the equilibrium state and the evaporation from the exposed surface. This experimental observation may be successfully used for the development of advanced high temperature coatings based on the ceramics of the Y2O3-ZrO2-HfO2 system.
AB - © 2014 Elsevier B.V. All rights reserved.Nano-particles of refractory oxides based on the Y2O3-ZrO2-HfO2 system (cubic phase) were synthesized using the glycol-citrate method. The dependence of the morphology and fineness of the powder obtained on the heat treatment conditions was considered. Vaporization processes and thermodynamic properties of ceramic powder in the Y2O3-ZrO2-HfO2 system were studied by the Knudsen effusion mass spectrometric method in the temperature range 2700-2925 K. It was found that at the temperature (2773 ± 40) K the ceramic powder containing Y2O3:ZrO2:HfO2 as 0.15:0.60:0.25 mol fractions underwent a congruent sublimation. The phenomenon observed was confirmed during ten hours vaporization under conditions intermediate to the equilibrium state and the evaporation from the exposed surface. This experimental observation may be successfully used for the development of advanced high temperature coatings based on the ceramics of the Y2O3-ZrO2-HfO2 system.
U2 - 10.1016/j.matchemphys.2014.12.037
DO - 10.1016/j.matchemphys.2014.12.037
M3 - Article
VL - 153
SP - 78
EP - 87
JO - Materials Chemistry and Physics
JF - Materials Chemistry and Physics
SN - 0254-0584
ER -
ID: 3925138