Synthesis, structure, and properties of new solid thermoplastic butadiene polymers

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Synthesis, structure, and properties of new solid thermoplastic butadiene polymers. / Ульянова, Д. М. ; Саблина, Н. А. ; Толстой, Петр Михайлович.

In: Russian Chemical Bulletin, Vol. 74, No. 7, 01.07.2025, p. 2202-2206.

Research output: Contribution to journal › Article › peer-review

Author

Ульянова, Д. М. ; Саблина, Н. А. ; Толстой, Петр Михайлович. / Synthesis, structure, and properties of new solid thermoplastic butadiene polymers. In: Russian Chemical Bulletin. 2025 ; Vol. 74, No. 7. pp. 2202-2206.

BibTeX

@article{103647ba91194ca585801cfd87aece90,

title = "Synthesis, structure, and properties of new solid thermoplastic butadiene polymers",

abstract = "It has been established for the first time that cationic polymerization of butadiene in the presence of the initiating system diethylaluminum chloride—allyl chloride allows the synthesis of fully soluble solid thermoplastic polymers with reduced unsaturation (40–48 mol.% of theoretical) and high glass transition (56–65 °C) and softening point (126–193 °C) temperatures. The structure of the synthesized polybutadiene macromolecules, including the structure of the head units consisting of allyl fragments of the polymerization initiator (allyl chloride) connected with the 1,4-trans-unit of polybutadiene, has been determined. The resulting polymers may find a practical application in the production of adhesive and sealing compositions.",

keywords = "allyl chloride, butadiene, cationic polymerization, diethylaluminum chloride, thermoplastic polymer",

author = "Ульянова, {Д. М.} and Саблина, {Н. А.} and Толстой, {Петр Михайлович}",

year = "2025",

month = jul,

day = "1",

doi = "10.1007/s11172-025-4705-4",

language = "English",

volume = "74",

pages = "2202--2206",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "7",

}

RIS

TY - JOUR

T1 - Synthesis, structure, and properties of new solid thermoplastic butadiene polymers

AU - Ульянова, Д. М.

AU - Саблина, Н. А.

AU - Толстой, Петр Михайлович

PY - 2025/7/1

Y1 - 2025/7/1

N2 - It has been established for the first time that cationic polymerization of butadiene in the presence of the initiating system diethylaluminum chloride—allyl chloride allows the synthesis of fully soluble solid thermoplastic polymers with reduced unsaturation (40–48 mol.% of theoretical) and high glass transition (56–65 °C) and softening point (126–193 °C) temperatures. The structure of the synthesized polybutadiene macromolecules, including the structure of the head units consisting of allyl fragments of the polymerization initiator (allyl chloride) connected with the 1,4-trans-unit of polybutadiene, has been determined. The resulting polymers may find a practical application in the production of adhesive and sealing compositions.

AB - It has been established for the first time that cationic polymerization of butadiene in the presence of the initiating system diethylaluminum chloride—allyl chloride allows the synthesis of fully soluble solid thermoplastic polymers with reduced unsaturation (40–48 mol.% of theoretical) and high glass transition (56–65 °C) and softening point (126–193 °C) temperatures. The structure of the synthesized polybutadiene macromolecules, including the structure of the head units consisting of allyl fragments of the polymerization initiator (allyl chloride) connected with the 1,4-trans-unit of polybutadiene, has been determined. The resulting polymers may find a practical application in the production of adhesive and sealing compositions.

KW - allyl chloride

KW - butadiene

KW - cationic polymerization

KW - diethylaluminum chloride

KW - thermoplastic polymer

UR - https://www.mendeley.com/catalogue/ca3a1667-5c58-38ce-8bc9-ab15db140732/

U2 - 10.1007/s11172-025-4705-4

DO - 10.1007/s11172-025-4705-4

M3 - Article

VL - 74

SP - 2202

EP - 2206

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7

ER -

ID: 142970287