Research output: Contribution to journal › Article
Synthesis, spectroscopic and electrochemical properties of axially symmetric fullerene-porphyrin dyad with a rigid pyrrolo[3,4-c]pyrrole spacer. / Konev, A.S.; Khlebnikov, A.F.; Nikiforova, T.G.; Virtsev, A.A.; Frauendorf, H.
In: Journal of Organic Chemistry, Vol. 78, No. 6, 2013, p. 2542-2552.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis, spectroscopic and electrochemical properties of axially symmetric fullerene-porphyrin dyad with a rigid pyrrolo[3,4-c]pyrrole spacer
AU - Konev, A.S.
AU - Khlebnikov, A.F.
AU - Nikiforova, T.G.
AU - Virtsev, A.A.
AU - Frauendorf, H.
PY - 2013
Y1 - 2013
N2 - A new approach to porphyrinofullerene donor-acceptor dyads, based on consecutive 1,3-dipolar cycloaddition of azomethine ylides, generated from bis-aziridinedicarboxylate, to C60 and to porphyrin with a maleimidophenyl substituent, was developed. A synthesis of the axially symmetric porphyrin-fullerene-C60 ensemble 5 with a novel rigid pyrrolo[3,4-c]pyrrolic linker was realized. Theoretical, electrochemical, and spectroscopic studies of compound 5 showed that it is capable of forming a charge-separated state. © 2013 American Chemical Society.
AB - A new approach to porphyrinofullerene donor-acceptor dyads, based on consecutive 1,3-dipolar cycloaddition of azomethine ylides, generated from bis-aziridinedicarboxylate, to C60 and to porphyrin with a maleimidophenyl substituent, was developed. A synthesis of the axially symmetric porphyrin-fullerene-C60 ensemble 5 with a novel rigid pyrrolo[3,4-c]pyrrolic linker was realized. Theoretical, electrochemical, and spectroscopic studies of compound 5 showed that it is capable of forming a charge-separated state. © 2013 American Chemical Society.
U2 - 10.1021/jo302763a
DO - 10.1021/jo302763a
M3 - Article
VL - 78
SP - 2542
EP - 2552
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 6
ER -
ID: 5628999