Research output: Contribution to journal › Article › peer-review
Synthesis, properties and applications of carbon nanomaterials functionalized with anionic groups. / Kharisova, Ksenia; Lukyanov, Daniil; Korusenko, Petr; Beletskii, Evgenii; Vereshchagin, Anatoliy; Levin, Oleg; Li, Ruopeng; Yang, Peixia; Alekseeva, Elena.
In: Nano-Structures and Nano-Objects, Vol. 39, 101258, 01.09.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis, properties and applications of carbon nanomaterials functionalized with anionic groups
AU - Kharisova, Ksenia
AU - Lukyanov, Daniil
AU - Korusenko, Petr
AU - Beletskii, Evgenii
AU - Vereshchagin, Anatoliy
AU - Levin, Oleg
AU - Li, Ruopeng
AU - Yang, Peixia
AU - Alekseeva, Elena
PY - 2024/9/1
Y1 - 2024/9/1
N2 - Anion-modified carbon nanomaterials (CNMs) represent a diverse class of functional nanomaterials that have attracted considerable interest due to their tunable properties and diverse applications. These materials are obtained by covalent attachment of negatively charged groups such as carboxylate, sulfonate/sulfate, and phosphonate to various CNMs, including carbon nanotubes, graphene, and carbon dots. The synthesis, characterization, and performance of these materials are affected by the type and quantity of anionic groups as well as the nature and morphology of the CNMs. This review provides a comprehensive overview of recent advances in anionic CNMs, including preparation methods, structural and surface analysis techniques, and applications in catalysis, ion exchange, membrane fabrication, electrochemical energy storage, and chemical sensing. Additionally, challenges and perspectives for future research in this emerging field will be discussed. While there are reviews on specific aspects of anionic CNMs, there is a lack of a comprehensive review on various negatively charged CNMs. The present review aims to address this gap by providing an overview of covalent modifications using carboxylate, sulfonate/sulfate, and phosphonate groups. The focus is on low molecular weight anionic fragments.
AB - Anion-modified carbon nanomaterials (CNMs) represent a diverse class of functional nanomaterials that have attracted considerable interest due to their tunable properties and diverse applications. These materials are obtained by covalent attachment of negatively charged groups such as carboxylate, sulfonate/sulfate, and phosphonate to various CNMs, including carbon nanotubes, graphene, and carbon dots. The synthesis, characterization, and performance of these materials are affected by the type and quantity of anionic groups as well as the nature and morphology of the CNMs. This review provides a comprehensive overview of recent advances in anionic CNMs, including preparation methods, structural and surface analysis techniques, and applications in catalysis, ion exchange, membrane fabrication, electrochemical energy storage, and chemical sensing. Additionally, challenges and perspectives for future research in this emerging field will be discussed. While there are reviews on specific aspects of anionic CNMs, there is a lack of a comprehensive review on various negatively charged CNMs. The present review aims to address this gap by providing an overview of covalent modifications using carboxylate, sulfonate/sulfate, and phosphonate groups. The focus is on low molecular weight anionic fragments.
KW - Carbon nanomaterials
KW - Anionic groups
KW - Sulfonation
KW - Carboxylation
KW - Graphene
KW - Carbon nanotubes
UR - https://www.mendeley.com/catalogue/00e7062e-b449-3760-a3db-1e7291748e22/
U2 - 10.1016/j.nanoso.2024.101258
DO - 10.1016/j.nanoso.2024.101258
M3 - Article
VL - 39
JO - Nano-Structures and Nano-Objects
JF - Nano-Structures and Nano-Objects
SN - 2352-507X
M1 - 101258
ER -
ID: 122216959