Properties of the monomolecular films containing hydrid as derivatives of porphyrine, ferrocene and hexacyanoferrates are considered. Surface properties of alkylferrocene monolayers are studied, their transferring conditions on a firm substrate are chosen. The film electrodes are created using obtained structures.The film electrodes usage as reference electrodes and electrodes of the II kind reversible to anion surface-active substances is shown.le Standard electrode potential for the system RIIIFc - RIIIFcF9Val is determined wich is equal (0,360+ 5)V.