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Synthesis of benzannelated sultams by intramolecular Pd-catalyzed arylation of tertiary sulfonamides. / Соколов, Виктор Владимирович; Рассадин, Валентин Анатольевич.

In: Beilstein Journal of Organic Chemistry, Vol. 13, 10.3762/bjoc.13.187, 12.09.2017, p. 1932-1939.

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@article{1d5846a8d91c446b94e35c504acbc310,
title = "Synthesis of benzannelated sultams by intramolecular Pd-catalyzed arylation of tertiary sulfonamides",
abstract = "A new and efficient approach to five- and six-membered benzannelated sultams by intramolecular C-arylation of tertiary1-(methoxycarbonyl)methanesulfonamides under palladium catalysis is described. In case of the α-toluenesulfonamide derivative,an unexpected formation of a 2,3-diarylindole was observed under the same conditions.",
keywords = "arylation; fused-ring systems; indole formation; palladium catalysis; sultams",
author = "Соколов, {Виктор Владимирович} and Рассадин, {Валентин Анатольевич}",
year = "2017",
month = sep,
day = "12",
doi = "10.3762/bjoc.13.187",
language = "English",
volume = "13",
pages = "1932--1939",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

RIS

TY - JOUR

T1 - Synthesis of benzannelated sultams by intramolecular Pd-catalyzed arylation of tertiary sulfonamides

AU - Соколов, Виктор Владимирович

AU - Рассадин, Валентин Анатольевич

PY - 2017/9/12

Y1 - 2017/9/12

N2 - A new and efficient approach to five- and six-membered benzannelated sultams by intramolecular C-arylation of tertiary1-(methoxycarbonyl)methanesulfonamides under palladium catalysis is described. In case of the α-toluenesulfonamide derivative,an unexpected formation of a 2,3-diarylindole was observed under the same conditions.

AB - A new and efficient approach to five- and six-membered benzannelated sultams by intramolecular C-arylation of tertiary1-(methoxycarbonyl)methanesulfonamides under palladium catalysis is described. In case of the α-toluenesulfonamide derivative,an unexpected formation of a 2,3-diarylindole was observed under the same conditions.

KW - arylation; fused-ring systems; indole formation; palladium catalysis; sultams

U2 - 10.3762/bjoc.13.187

DO - 10.3762/bjoc.13.187

M3 - Article

VL - 13

SP - 1932

EP - 1939

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

M1 - 10.3762/bjoc.13.187

ER -

ID: 9328650