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Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering. / Simonenko, Tatiana L.; Kalinina, Marina V.; Simonenko, Nikolay P.; Simonenko, Elizaveta P.; Glumov, Oleg V.; Mel'nikova, Natalia A.; Murin, Igor V.; Shichalin, Oleg O.; Papynov, Evgeniy K.; Shilova, Olga A.; Sevastyanov, Vladimir G.; Kuznetsov, Nikolay T.

In: International Journal of Hydrogen Energy, Vol. 44, No. 36, 26.07.2019, p. 20345-20354.

Research output: Contribution to journal › Article › peer-review

Harvard

Simonenko, TL, Kalinina, MV, Simonenko, NP, Simonenko, EP, Glumov, OV, Mel'nikova, NA, Murin, IV, Shichalin, OO, Papynov, EK, Shilova, OA, Sevastyanov, VG & Kuznetsov, NT 2019, 'Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering', International Journal of Hydrogen Energy, vol. 44, no. 36, pp. 20345-20354. https://doi.org/10.1016/j.ijhydene.2019.05.231

APA

Simonenko, T. L., Kalinina, M. V., Simonenko, N. P., Simonenko, E. P., Glumov, O. V., Mel'nikova, N. A., Murin, I. V., Shichalin, O. O., Papynov, E. K., Shilova, O. A., Sevastyanov, V. G., & Kuznetsov, N. T. (2019). Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering. International Journal of Hydrogen Energy, 44(36), 20345-20354. https://doi.org/10.1016/j.ijhydene.2019.05.231

Vancouver

Simonenko TL, Kalinina MV, Simonenko NP, Simonenko EP, Glumov OV, Mel'nikova NA et al. Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering. International Journal of Hydrogen Energy. 2019 Jul 26;44(36):20345-20354. https://doi.org/10.1016/j.ijhydene.2019.05.231

Author

Simonenko, Tatiana L. ; Kalinina, Marina V. ; Simonenko, Nikolay P. ; Simonenko, Elizaveta P. ; Glumov, Oleg V. ; Mel'nikova, Natalia A. ; Murin, Igor V. ; Shichalin, Oleg O. ; Papynov, Evgeniy K. ; Shilova, Olga A. ; Sevastyanov, Vladimir G. ; Kuznetsov, Nikolay T. / Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering. In: International Journal of Hydrogen Energy. 2019 ; Vol. 44, No. 36. pp. 20345-20354.

BibTeX

@article{dd8adc24cb174135806019492862b165,
title = "Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering",
abstract = "Using a citrate-nitrate process, BaCe0.9-xZrxY0.1O3-δ (x = 0, 0.5, 0.6, 0.7 and 0.8) nanopowders were synthesized, on the basis of which proton-conducting solid electrolytes (average size of coherent scattering region (CSR) - 15–53 nm) were obtained by spark plasma sintering (SPS) at a low temperature (900°С). The dependence of phase composition, microstructure and electrophysical properties of the obtained samples on ZrO2 content and consolidation conditions was established. It was found that the BaCe0.4Zr0,5Y0.1O3-δ solid solution had the highest electrical conductivity among zirconium-containing ceramic materials in the studied concentration range. It was shown that SPS is a promising method for obtaining solid electrolytes for proton-conducting solid oxide fuel cells (PCFC) at lower temperatures (by 400–500°С), compared to traditionally-used temperature conditions (1400–1800 °C).",
keywords = "BCZY, Citrate-nitrate synthesis, PCFC, Proton conductors, Solid electrolyte, Spark plasma sintering, BACE0.8-XZRXY0.2O3-DELTA, ELECTROLYTE, TRANSPORT-PROPERTIES, ELECTRICAL-PROPERTIES, CHEMICAL-STABILITY, DOPED BAZRO3, CONDUCTIVITY, OXIDE FUEL-CELLS, MICROSTRUCTURE, ELECTROCHEMICAL PERFORMANCE",
author = "Simonenko, {Tatiana L.} and Kalinina, {Marina V.} and Simonenko, {Nikolay P.} and Simonenko, {Elizaveta P.} and Glumov, {Oleg V.} and Mel'nikova, {Natalia A.} and Murin, {Igor V.} and Shichalin, {Oleg O.} and Papynov, {Evgeniy K.} and Shilova, {Olga A.} and Sevastyanov, {Vladimir G.} and Kuznetsov, {Nikolay T.}",
year = "2019",
month = jul,
day = "26",
doi = "10.1016/j.ijhydene.2019.05.231",
language = "English",
volume = "44",
pages = "20345--20354",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier",
number = "36",

}

RIS

TY - JOUR

T1 - Synthesis of BaCe0.9-xZrxY0.1O3-δ nanopowders and the study of proton conductors fabricated on their basis by low-temperature spark plasma sintering

AU - Simonenko, Tatiana L.

AU - Kalinina, Marina V.

AU - Simonenko, Nikolay P.

AU - Simonenko, Elizaveta P.

AU - Glumov, Oleg V.

AU - Mel'nikova, Natalia A.

AU - Murin, Igor V.

AU - Shichalin, Oleg O.

AU - Papynov, Evgeniy K.

AU - Shilova, Olga A.

AU - Sevastyanov, Vladimir G.

AU - Kuznetsov, Nikolay T.

PY - 2019/7/26

Y1 - 2019/7/26

N2 - Using a citrate-nitrate process, BaCe0.9-xZrxY0.1O3-δ (x = 0, 0.5, 0.6, 0.7 and 0.8) nanopowders were synthesized, on the basis of which proton-conducting solid electrolytes (average size of coherent scattering region (CSR) - 15–53 nm) were obtained by spark plasma sintering (SPS) at a low temperature (900°С). The dependence of phase composition, microstructure and electrophysical properties of the obtained samples on ZrO2 content and consolidation conditions was established. It was found that the BaCe0.4Zr0,5Y0.1O3-δ solid solution had the highest electrical conductivity among zirconium-containing ceramic materials in the studied concentration range. It was shown that SPS is a promising method for obtaining solid electrolytes for proton-conducting solid oxide fuel cells (PCFC) at lower temperatures (by 400–500°С), compared to traditionally-used temperature conditions (1400–1800 °C).

AB - Using a citrate-nitrate process, BaCe0.9-xZrxY0.1O3-δ (x = 0, 0.5, 0.6, 0.7 and 0.8) nanopowders were synthesized, on the basis of which proton-conducting solid electrolytes (average size of coherent scattering region (CSR) - 15–53 nm) were obtained by spark plasma sintering (SPS) at a low temperature (900°С). The dependence of phase composition, microstructure and electrophysical properties of the obtained samples on ZrO2 content and consolidation conditions was established. It was found that the BaCe0.4Zr0,5Y0.1O3-δ solid solution had the highest electrical conductivity among zirconium-containing ceramic materials in the studied concentration range. It was shown that SPS is a promising method for obtaining solid electrolytes for proton-conducting solid oxide fuel cells (PCFC) at lower temperatures (by 400–500°С), compared to traditionally-used temperature conditions (1400–1800 °C).

KW - BCZY

KW - Citrate-nitrate synthesis

KW - PCFC

KW - Proton conductors

KW - Solid electrolyte

KW - Spark plasma sintering

KW - BACE0.8-XZRXY0.2O3-DELTA

KW - ELECTROLYTE

KW - TRANSPORT-PROPERTIES

KW - ELECTRICAL-PROPERTIES

KW - CHEMICAL-STABILITY

KW - DOPED BAZRO3

KW - CONDUCTIVITY

KW - OXIDE FUEL-CELLS

KW - MICROSTRUCTURE

KW - ELECTROCHEMICAL PERFORMANCE

UR - http://www.scopus.com/inward/record.url?scp=85067542792&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/synthesis-bace09xzrxy01o3%CE%B4-nanopowders-study-proton-conductors-fabricated-basis-lowtemperature-spark

U2 - 10.1016/j.ijhydene.2019.05.231

DO - 10.1016/j.ijhydene.2019.05.231

M3 - Article

AN - SCOPUS:85067542792

VL - 44

SP - 20345

EP - 20354

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 36

ER -

ID: 43419988