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Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine. / Balova, I. A.; Remizova, L. A.; Pashchenko, V. Yu.

In: Russian Journal of Organic Chemistry, Vol. 35, No. 10, 10.1999, p. 1476-1479.

Research output: Contribution to journal › Article › peer-review

Harvard

Balova, IA, Remizova, LA & Pashchenko, VY 1999, 'Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine', Russian Journal of Organic Chemistry, vol. 35, no. 10, pp. 1476-1479.

APA

Balova, I. A., Remizova, L. A., & Pashchenko, V. Y. (1999). Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine. Russian Journal of Organic Chemistry, 35(10), 1476-1479.

Vancouver

Balova IA, Remizova LA, Pashchenko VY. Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine. Russian Journal of Organic Chemistry. 1999 Oct;35(10):1476-1479.

Author

Balova, I. A. ; Remizova, L. A. ; Pashchenko, V. Yu. / Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine. In: Russian Journal of Organic Chemistry. 1999 ; Vol. 35, No. 10. pp. 1476-1479.

BibTeX

@article{cbc5a1519d9445cfb778974e974e710b,
title = "Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine",
abstract = "Reactions of o-phenylenediamine with 2-propynyl bromide and 1-bromo-2,4-undecadiyne in a nonpolar solvent lead to formation of the corresponding N-monoalkynylated products. Increase in the solvent polarity favors alkynylation at the second amino group to give symmetric N,N′-disubstituted product. Synthesis of amphiphilic diacetylenic o-phenylenediamine derivatives by reaction with 1-bromo-2,4-undecadiyne provides better yields of the N-alkynylated products than the Cadiot-Chodkiewicz method. A series of new acetylenic and diacetylenic derivatives of o-phenylenediamine was thus isolated and characterized.",
author = "Balova, {I. A.} and Remizova, {L. A.} and Pashchenko, {V. Yu}",
year = "1999",
month = oct,
language = "English",
volume = "35",
pages = "1476--1479",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis of acetylenic and diacetylenic diamines by alkynylation of o-phenylenediamine

AU - Balova, I. A.

AU - Remizova, L. A.

AU - Pashchenko, V. Yu

PY - 1999/10

Y1 - 1999/10

N2 - Reactions of o-phenylenediamine with 2-propynyl bromide and 1-bromo-2,4-undecadiyne in a nonpolar solvent lead to formation of the corresponding N-monoalkynylated products. Increase in the solvent polarity favors alkynylation at the second amino group to give symmetric N,N′-disubstituted product. Synthesis of amphiphilic diacetylenic o-phenylenediamine derivatives by reaction with 1-bromo-2,4-undecadiyne provides better yields of the N-alkynylated products than the Cadiot-Chodkiewicz method. A series of new acetylenic and diacetylenic derivatives of o-phenylenediamine was thus isolated and characterized.

AB - Reactions of o-phenylenediamine with 2-propynyl bromide and 1-bromo-2,4-undecadiyne in a nonpolar solvent lead to formation of the corresponding N-monoalkynylated products. Increase in the solvent polarity favors alkynylation at the second amino group to give symmetric N,N′-disubstituted product. Synthesis of amphiphilic diacetylenic o-phenylenediamine derivatives by reaction with 1-bromo-2,4-undecadiyne provides better yields of the N-alkynylated products than the Cadiot-Chodkiewicz method. A series of new acetylenic and diacetylenic derivatives of o-phenylenediamine was thus isolated and characterized.

UR - http://www.scopus.com/inward/record.url?scp=0033233885&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0033233885

VL - 35

SP - 1476

EP - 1479

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 10

ER -

ID: 96688930