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Synthesis of a Water Dispersion of the PEDOT:PSS/Pd Composite and Its Use for the Fabrication of an Electrochemical Sensor for Hydrazine. / Tolstopyatova, E.G.; Saidov, Y.K.; Smolin, A.M.; Novoselov, N.P.; Kondrat’ev, V.V.

In: Journal of Analytical Chemistry, Vol. 71, No. 2, 2016, p. 195-200.

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Tolstopyatova, E.G. ; Saidov, Y.K. ; Smolin, A.M. ; Novoselov, N.P. ; Kondrat’ev, V.V. / Synthesis of a Water Dispersion of the PEDOT:PSS/Pd Composite and Its Use for the Fabrication of an Electrochemical Sensor for Hydrazine. In: Journal of Analytical Chemistry. 2016 ; Vol. 71, No. 2. pp. 195-200.

BibTeX

@article{859d0525fd234ef195d87895f804a658,
title = "Synthesis of a Water Dispersion of the PEDOT:PSS/Pd Composite and Its Use for the Fabrication of an Electrochemical Sensor for Hydrazine",
abstract = "Conditions are studied for the synthesis of water dispersions of polymer composites containing palladium and the possibility of their use for the fabrication of modified electrodes is estimated. Water dispersions of the polymer poly(3,4-ethylenedioxythiophene), including a polystyrene sulfate polyanion (PEDOT:PSS) and Pd particles, were obtained by the redox reaction of Pd(II) with the polymer. The electrochemical behavior of composite PEDOT:PSS/Pd films in the medium of a phosphate buffer solution with pH 6.86 is studied. It is shown that, in the presence of hydrazine in a phosphate buffer solution, one wave of hydrazine oxidation on metal inclusions, Pd particles, is observed on the electrode. Specific features of the process of hydrazine oxidation are studied and a possibility using the obtained material for the creation of an electrochemical sensor for hydrazine is demonstrated.",
author = "E.G. Tolstopyatova and Y.K. Saidov and A.M. Smolin and N.P. Novoselov and V.V. Kondrat{\textquoteright}ev",
year = "2016",
doi = "10.1134/S1061934816020131",
language = "не определен",
volume = "71",
pages = "195--200",
journal = "Journal of Analytical Chemistry",
issn = "1061-9348",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Synthesis of a Water Dispersion of the PEDOT:PSS/Pd Composite and Its Use for the Fabrication of an Electrochemical Sensor for Hydrazine

AU - Tolstopyatova, E.G.

AU - Saidov, Y.K.

AU - Smolin, A.M.

AU - Novoselov, N.P.

AU - Kondrat’ev, V.V.

PY - 2016

Y1 - 2016

N2 - Conditions are studied for the synthesis of water dispersions of polymer composites containing palladium and the possibility of their use for the fabrication of modified electrodes is estimated. Water dispersions of the polymer poly(3,4-ethylenedioxythiophene), including a polystyrene sulfate polyanion (PEDOT:PSS) and Pd particles, were obtained by the redox reaction of Pd(II) with the polymer. The electrochemical behavior of composite PEDOT:PSS/Pd films in the medium of a phosphate buffer solution with pH 6.86 is studied. It is shown that, in the presence of hydrazine in a phosphate buffer solution, one wave of hydrazine oxidation on metal inclusions, Pd particles, is observed on the electrode. Specific features of the process of hydrazine oxidation are studied and a possibility using the obtained material for the creation of an electrochemical sensor for hydrazine is demonstrated.

AB - Conditions are studied for the synthesis of water dispersions of polymer composites containing palladium and the possibility of their use for the fabrication of modified electrodes is estimated. Water dispersions of the polymer poly(3,4-ethylenedioxythiophene), including a polystyrene sulfate polyanion (PEDOT:PSS) and Pd particles, were obtained by the redox reaction of Pd(II) with the polymer. The electrochemical behavior of composite PEDOT:PSS/Pd films in the medium of a phosphate buffer solution with pH 6.86 is studied. It is shown that, in the presence of hydrazine in a phosphate buffer solution, one wave of hydrazine oxidation on metal inclusions, Pd particles, is observed on the electrode. Specific features of the process of hydrazine oxidation are studied and a possibility using the obtained material for the creation of an electrochemical sensor for hydrazine is demonstrated.

U2 - 10.1134/S1061934816020131

DO - 10.1134/S1061934816020131

M3 - статья

VL - 71

SP - 195

EP - 200

JO - Journal of Analytical Chemistry

JF - Journal of Analytical Chemistry

SN - 1061-9348

IS - 2

ER -

ID: 7591528