Synthesis of [188ReX(CO)5] (X = Cl, Br, and I)

Standard

Synthesis of [¹⁸⁸ReX(CO)₅] (X = Cl, Br, and I). / Miroslavov, A. E.; Alekseev, I. E.; Tyupina, M. Yu; Lumpov, A. A.; Stepanova, E. S.; Kol’tsov, V. V.; Sidorenko, G. V.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 308, No. 3, 01.06.2016, p. 1039-1042.

Research output: Contribution to journal › Article › peer-review

Harvard

Miroslavov, AE, Alekseev, IE, Tyupina, MY, Lumpov, AA, Stepanova, ES, Kol’tsov, VV & Sidorenko, GV 2016, 'Synthesis of [¹⁸⁸ReX(CO)₅] (X = Cl, Br, and I)', Journal of Radioanalytical and Nuclear Chemistry, vol. 308, no. 3, pp. 1039-1042. https://doi.org/10.1007/s10967-015-4558-7

APA

Miroslavov, A. E., Alekseev, I. E., Tyupina, M. Y., Lumpov, A. A., Stepanova, E. S., Kol’tsov, V. V., & Sidorenko, G. V. (2016). Synthesis of [¹⁸⁸ReX(CO)₅] (X = Cl, Br, and I). Journal of Radioanalytical and Nuclear Chemistry, 308(3), 1039-1042. https://doi.org/10.1007/s10967-015-4558-7

Vancouver

Miroslavov AE, Alekseev IE, Tyupina MY, Lumpov AA, Stepanova ES, Kol’tsov VV et al. Synthesis of [¹⁸⁸ReX(CO)₅] (X = Cl, Br, and I). Journal of Radioanalytical and Nuclear Chemistry. 2016 Jun 1;308(3):1039-1042. https://doi.org/10.1007/s10967-015-4558-7

Author

Miroslavov, A. E. ; Alekseev, I. E. ; Tyupina, M. Yu ; Lumpov, A. A. ; Stepanova, E. S. ; Kol’tsov, V. V. ; Sidorenko, G. V. / Synthesis of [¹⁸⁸ReX(CO)₅] (X = Cl, Br, and I). In: Journal of Radioanalytical and Nuclear Chemistry. 2016 ; Vol. 308, No. 3. pp. 1039-1042.

BibTeX

@article{7ed2539a6bfc441fbafa0b71dfe78bf1,

title = "Synthesis of [188ReX(CO)5] (X = Cl, Br, and I)",

abstract = "Radiochemically pure [188ReX(CO)5] (X = Cl, Br, and I) were prepared for the first time by high-pressure carbonylation of 188ReO4 − with carbon monoxide in an aqueous solution in the presence of halide ions at 210 °C. The complexes were isolated at the n.c.a. level from the reaction mixture by gas-phase transport with carbon monoxide at a high pressure. The procedure allows obtaining the target compounds in any appropriate solvent (aqueous and nonaqueous), which may open new synthetic prospects for the development of novel therapeutic radiopharmaceuticals.",

keywords = "Autoclave, Carbonyl, Gas-phase transport, High-pressure synthesis, No carrier added Re, Radiopharmaceuticals",

author = "Miroslavov, {A. E.} and Alekseev, {I. E.} and Tyupina, {M. Yu} and Lumpov, {A. A.} and Stepanova, {E. S.} and Kol{\textquoteright}tsov, {V. V.} and Sidorenko, {G. V.}",

year = "2016",

month = jun,

day = "1",

doi = "10.1007/s10967-015-4558-7",

language = "English",

volume = "308",

pages = "1039--1042",

journal = "Journal of Radioanalytical and Nuclear Chemistry",

issn = "0236-5731",

publisher = "Springer Nature",

number = "3",

}

RIS

TY - JOUR

T1 - Synthesis of [188ReX(CO)5] (X = Cl, Br, and I)

AU - Miroslavov, A. E.

AU - Alekseev, I. E.

AU - Tyupina, M. Yu

AU - Lumpov, A. A.

AU - Stepanova, E. S.

AU - Kol’tsov, V. V.

AU - Sidorenko, G. V.

PY - 2016/6/1

Y1 - 2016/6/1

N2 - Radiochemically pure [188ReX(CO)5] (X = Cl, Br, and I) were prepared for the first time by high-pressure carbonylation of 188ReO4 − with carbon monoxide in an aqueous solution in the presence of halide ions at 210 °C. The complexes were isolated at the n.c.a. level from the reaction mixture by gas-phase transport with carbon monoxide at a high pressure. The procedure allows obtaining the target compounds in any appropriate solvent (aqueous and nonaqueous), which may open new synthetic prospects for the development of novel therapeutic radiopharmaceuticals.

AB - Radiochemically pure [188ReX(CO)5] (X = Cl, Br, and I) were prepared for the first time by high-pressure carbonylation of 188ReO4 − with carbon monoxide in an aqueous solution in the presence of halide ions at 210 °C. The complexes were isolated at the n.c.a. level from the reaction mixture by gas-phase transport with carbon monoxide at a high pressure. The procedure allows obtaining the target compounds in any appropriate solvent (aqueous and nonaqueous), which may open new synthetic prospects for the development of novel therapeutic radiopharmaceuticals.

KW - Autoclave

KW - Carbonyl

KW - Gas-phase transport

KW - High-pressure synthesis

KW - No carrier added Re

KW - Radiopharmaceuticals

UR - http://www.scopus.com/inward/record.url?scp=84945256785&partnerID=8YFLogxK

U2 - 10.1007/s10967-015-4558-7

DO - 10.1007/s10967-015-4558-7

M3 - Article

AN - SCOPUS:84945256785

VL - 308

SP - 1039

EP - 1042

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

SN - 0236-5731

IS - 3

ER -

ID: 76835031