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Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+. / Kuznetsov, Artem; Zholdas, Yerassyl; Горелова, Людмила Александровна; Fedorenko, Anastasiya; Ryadun, Aleksey A.; Seryotkin, Y.V.; Shevchenko, Vyacheslav; Кох, А.Е.; Klimov, Alexandr; Кох, Константин Александрович.

In: Crystal Growth and Design, Vol. 24, No. 13, 03.07.2024, p. 5478-5485.

Research output: Contribution to journalArticlepeer-review

Harvard

Kuznetsov, A, Zholdas, Y, Горелова, ЛА, Fedorenko, A, Ryadun, AA, Seryotkin, YV, Shevchenko, V, Кох, АЕ, Klimov, A & Кох, КА 2024, 'Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+', Crystal Growth and Design, vol. 24, no. 13, pp. 5478-5485. https://doi.org/10.1021/acs.cgd.4c00140

APA

Kuznetsov, A., Zholdas, Y., Горелова, Л. А., Fedorenko, A., Ryadun, A. A., Seryotkin, Y. V., Shevchenko, V., Кох, А. Е., Klimov, A., & Кох, К. А. (2024). Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+. Crystal Growth and Design, 24(13), 5478-5485. https://doi.org/10.1021/acs.cgd.4c00140

Vancouver

Kuznetsov A, Zholdas Y, Горелова ЛА, Fedorenko A, Ryadun AA, Seryotkin YV et al. Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+. Crystal Growth and Design. 2024 Jul 3;24(13):5478-5485. https://doi.org/10.1021/acs.cgd.4c00140

Author

Kuznetsov, Artem ; Zholdas, Yerassyl ; Горелова, Людмила Александровна ; Fedorenko, Anastasiya ; Ryadun, Aleksey A. ; Seryotkin, Y.V. ; Shevchenko, Vyacheslav ; Кох, А.Е. ; Klimov, Alexandr ; Кох, Константин Александрович. / Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+. In: Crystal Growth and Design. 2024 ; Vol. 24, No. 13. pp. 5478-5485.

BibTeX

@article{023359c13fba4d4686dc8a9ee6134d67,
title = "Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+",
abstract = "KSrY(BO3)2: Tb3+ and Tb4+ solid solutions have been obtained using the solid-state synthesis and top-seeded solution growth method from the KF flux. Comparing the two types of Tb spectra 3d3/2 TbO2 (Tb4+) and Na3Tb(BO3)2 (Tb3+) with annealing in air of the KSrTb(BO3)2 crystal, X-ray photoelectron spectroscopy (XPS) revealed that the crystal contains about 15% of Tb4+. The entire Y/Tb series has polymorphic phase transitions that occur at temperatures between 550 and 600 °C. Synthesis and subsequent treatment methodology have an impact on the resulting Tb3+/Tb4+ ratio in the sample. The best luminescent properties were measured on the composition KSrY0.9Tb0.1(BO3)2, which was annealed at 700 °C under a hydrogen flow and cooled slowly.",
keywords = "Annealing (metallurgy), x-ray photoelectron spectroscopy, crystal structure, crystals, terbium",
author = "Artem Kuznetsov and Yerassyl Zholdas and Горелова, {Людмила Александровна} and Anastasiya Fedorenko and Ryadun, {Aleksey A.} and Y.V. Seryotkin and Vyacheslav Shevchenko and А.Е. Кох and Alexandr Klimov and Кох, {Константин Александрович}",
year = "2024",
month = jul,
day = "3",
doi = "10.1021/acs.cgd.4c00140",
language = "English",
volume = "24",
pages = "5478--5485",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Synthesis, Growth, and Luminescence Properties of Rare Earth Borates KSrY(BO3)2: Tb3+ and Tb4+

AU - Kuznetsov, Artem

AU - Zholdas, Yerassyl

AU - Горелова, Людмила Александровна

AU - Fedorenko, Anastasiya

AU - Ryadun, Aleksey A.

AU - Seryotkin, Y.V.

AU - Shevchenko, Vyacheslav

AU - Кох, А.Е.

AU - Klimov, Alexandr

AU - Кох, Константин Александрович

PY - 2024/7/3

Y1 - 2024/7/3

N2 - KSrY(BO3)2: Tb3+ and Tb4+ solid solutions have been obtained using the solid-state synthesis and top-seeded solution growth method from the KF flux. Comparing the two types of Tb spectra 3d3/2 TbO2 (Tb4+) and Na3Tb(BO3)2 (Tb3+) with annealing in air of the KSrTb(BO3)2 crystal, X-ray photoelectron spectroscopy (XPS) revealed that the crystal contains about 15% of Tb4+. The entire Y/Tb series has polymorphic phase transitions that occur at temperatures between 550 and 600 °C. Synthesis and subsequent treatment methodology have an impact on the resulting Tb3+/Tb4+ ratio in the sample. The best luminescent properties were measured on the composition KSrY0.9Tb0.1(BO3)2, which was annealed at 700 °C under a hydrogen flow and cooled slowly.

AB - KSrY(BO3)2: Tb3+ and Tb4+ solid solutions have been obtained using the solid-state synthesis and top-seeded solution growth method from the KF flux. Comparing the two types of Tb spectra 3d3/2 TbO2 (Tb4+) and Na3Tb(BO3)2 (Tb3+) with annealing in air of the KSrTb(BO3)2 crystal, X-ray photoelectron spectroscopy (XPS) revealed that the crystal contains about 15% of Tb4+. The entire Y/Tb series has polymorphic phase transitions that occur at temperatures between 550 and 600 °C. Synthesis and subsequent treatment methodology have an impact on the resulting Tb3+/Tb4+ ratio in the sample. The best luminescent properties were measured on the composition KSrY0.9Tb0.1(BO3)2, which was annealed at 700 °C under a hydrogen flow and cooled slowly.

KW - Annealing (metallurgy)

KW - x-ray photoelectron spectroscopy

KW - crystal structure

KW - crystals

KW - terbium

UR - https://www.mendeley.com/catalogue/f65e87ce-4478-33ca-8e9d-b80f319fed39/

U2 - 10.1021/acs.cgd.4c00140

DO - 10.1021/acs.cgd.4c00140

M3 - Article

VL - 24

SP - 5478

EP - 5485

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 13

ER -

ID: 121590913