Standard

Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd) : The new perspectives of solid-state double-exchange synthesis. / Charkin, Dmitri O.; Karpov, Andrey S.; Kazakov, Sergey M.; Plokhikh, Igor V.; Zadoya, Anastasiya I.; Kuznetsov, Alexey N.; Maslakov, Konstantin I.; Teterin, Anton Yu; Teterin, Yury A.; Zaloga, Alexander N.; Siidra, Oleg I.

In: Journal of Solid State Chemistry, Vol. 277, 01.09.2019, p. 163-168.

Research output: Contribution to journal › Article › peer-review

Harvard

Charkin, DO, Karpov, AS, Kazakov, SM, Plokhikh, IV, Zadoya, AI, Kuznetsov, AN, Maslakov, KI, Teterin, AY, Teterin, YA, Zaloga, AN & Siidra, OI 2019, 'Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd): The new perspectives of solid-state double-exchange synthesis', Journal of Solid State Chemistry, vol. 277, pp. 163-168. https://doi.org/10.1016/j.jssc.2019.06.007

APA

Charkin, D. O., Karpov, A. S., Kazakov, S. M., Plokhikh, I. V., Zadoya, A. I., Kuznetsov, A. N., Maslakov, K. I., Teterin, A. Y., Teterin, Y. A., Zaloga, A. N., & Siidra, O. I. (2019). Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd): The new perspectives of solid-state double-exchange synthesis. Journal of Solid State Chemistry, 277, 163-168. https://doi.org/10.1016/j.jssc.2019.06.007

Vancouver

Charkin DO, Karpov AS, Kazakov SM, Plokhikh IV, Zadoya AI, Kuznetsov AN et al. Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd): The new perspectives of solid-state double-exchange synthesis. Journal of Solid State Chemistry. 2019 Sep 1;277:163-168. https://doi.org/10.1016/j.jssc.2019.06.007

Author

Charkin, Dmitri O. ; Karpov, Andrey S. ; Kazakov, Sergey M. ; Plokhikh, Igor V. ; Zadoya, Anastasiya I. ; Kuznetsov, Alexey N. ; Maslakov, Konstantin I. ; Teterin, Anton Yu ; Teterin, Yury A. ; Zaloga, Alexander N. ; Siidra, Oleg I. / Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd) : The new perspectives of solid-state double-exchange synthesis. In: Journal of Solid State Chemistry. 2019 ; Vol. 277. pp. 163-168.

BibTeX

@article{0866a79faa8241f6b5b489789c711a09,
title = "Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd): The new perspectives of solid-state double-exchange synthesis",
abstract = "Three rare-earth oxide selenates Ln2O2SeO4 (Ln = La, Pr, Nd) have been prepared via double-exchange solid-state reactions between respective LnOCl oxyhalides and potassium selenate. This approach succeeded to obtain single-phase specimens of La2O2SeO4 and Nd2O2SeO4, previously known as transients upon thermal decomposition of the corresponding selenates, as well as a new compound Pr2O2SeO4. Refinement of their crystal structures from powder X-ray diffraction data confirmed previous attributions to the grandreefite (Pb2F2SO4) structure type observed also for the Ln2O2SO4 oxide sulfates. According to polythermic X-ray studies, La2O2SeO4 is stable until at least 700 °C. All compounds were characterized by infrared and X-ray photoelectron spectroscopy.",
keywords = "Crystal structure, Double-exchange solid state reactions, Rare-earth compounds, Selenates",
author = "Charkin, {Dmitri O.} and Karpov, {Andrey S.} and Kazakov, {Sergey M.} and Plokhikh, {Igor V.} and Zadoya, {Anastasiya I.} and Kuznetsov, {Alexey N.} and Maslakov, {Konstantin I.} and Teterin, {Anton Yu} and Teterin, {Yury A.} and Zaloga, {Alexander N.} and Siidra, {Oleg I.}",
year = "2019",
month = sep,
day = "1",
doi = "10.1016/j.jssc.2019.06.007",
language = "English",
volume = "277",
pages = "163--168",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd)

T2 - The new perspectives of solid-state double-exchange synthesis

AU - Charkin, Dmitri O.

AU - Karpov, Andrey S.

AU - Kazakov, Sergey M.

AU - Plokhikh, Igor V.

AU - Zadoya, Anastasiya I.

AU - Kuznetsov, Alexey N.

AU - Maslakov, Konstantin I.

AU - Teterin, Anton Yu

AU - Teterin, Yury A.

AU - Zaloga, Alexander N.

AU - Siidra, Oleg I.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Three rare-earth oxide selenates Ln2O2SeO4 (Ln = La, Pr, Nd) have been prepared via double-exchange solid-state reactions between respective LnOCl oxyhalides and potassium selenate. This approach succeeded to obtain single-phase specimens of La2O2SeO4 and Nd2O2SeO4, previously known as transients upon thermal decomposition of the corresponding selenates, as well as a new compound Pr2O2SeO4. Refinement of their crystal structures from powder X-ray diffraction data confirmed previous attributions to the grandreefite (Pb2F2SO4) structure type observed also for the Ln2O2SO4 oxide sulfates. According to polythermic X-ray studies, La2O2SeO4 is stable until at least 700 °C. All compounds were characterized by infrared and X-ray photoelectron spectroscopy.

AB - Three rare-earth oxide selenates Ln2O2SeO4 (Ln = La, Pr, Nd) have been prepared via double-exchange solid-state reactions between respective LnOCl oxyhalides and potassium selenate. This approach succeeded to obtain single-phase specimens of La2O2SeO4 and Nd2O2SeO4, previously known as transients upon thermal decomposition of the corresponding selenates, as well as a new compound Pr2O2SeO4. Refinement of their crystal structures from powder X-ray diffraction data confirmed previous attributions to the grandreefite (Pb2F2SO4) structure type observed also for the Ln2O2SO4 oxide sulfates. According to polythermic X-ray studies, La2O2SeO4 is stable until at least 700 °C. All compounds were characterized by infrared and X-ray photoelectron spectroscopy.

KW - Crystal structure

KW - Double-exchange solid state reactions

KW - Rare-earth compounds

KW - Selenates

UR - http://www.scopus.com/inward/record.url?scp=85067183025&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2019.06.007

DO - 10.1016/j.jssc.2019.06.007

M3 - Article

AN - SCOPUS:85067183025

VL - 277

SP - 163

EP - 168

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

ID: 47922060