Synthesis and structure of copper(I) halide complexes with halogen-functionalized isocyanide ligands

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Synthesis and structure of copper(I) halide complexes with halogen-functionalized isocyanide ligands. / Власова, Василиса ; Тойкка, Юлия Николаевна; Суслонов, Виталий Валерьевич; Смирнов, Андрей Сергеевич ; Бокач, Надежда Арсеньевна.

In: Russian Journal of General Chemistry, Vol. 94, No. 7, 30.08.2024, p. 1682-1688.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{916ce17520b84424bc544f0d2ed4cdc7,

title = "Synthesis and structure of copper(I) halide complexes with halogen-functionalized isocyanide ligands",

abstract = "Abstract: Eleven copper(I) halide complexes [CuX(CNR)3] (X = Cl, Br; R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2,6-Br2, C6H3-2-Br-6-Me; X = I, R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2-Br-6-Me) bearing halogen-functionalized aromatic isocyanide ligands were synthesized. The compounds were characterized by atomic emission spectroscopy (Cu), IR, 1H NMR spectroscopy and high-resolution mass spectrometry. The structure of nine compounds was determined by X-ray diffraction. Structural studies allow to reveal that the supramolecular structure of the complexes is based on weak C–H···X (X = Cl, Br, I) interactions and π-stacking of the aromatic rings of isocyanide ligands.",

keywords = "X-ray diffraction, copper(I) complexes, isocyanides, noncovalent interactions",

author = "Василиса Власова and Тойкка, {Юлия Николаевна} and Суслонов, {Виталий Валерьевич} and Смирнов, {Андрей Сергеевич} and Бокач, {Надежда Арсеньевна}",

year = "2024",

month = aug,

day = "30",

doi = "10.1134/S1070363224070107",

language = "English",

volume = "94",

pages = "1682--1688",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "7",

}

RIS

TY - JOUR

T1 - Synthesis and structure of copper(I) halide complexes with halogen-functionalized isocyanide ligands

AU - Власова, Василиса

AU - Тойкка, Юлия Николаевна

AU - Суслонов, Виталий Валерьевич

AU - Смирнов, Андрей Сергеевич

AU - Бокач, Надежда Арсеньевна

PY - 2024/8/30

Y1 - 2024/8/30

N2 - Abstract: Eleven copper(I) halide complexes [CuX(CNR)3] (X = Cl, Br; R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2,6-Br2, C6H3-2-Br-6-Me; X = I, R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2-Br-6-Me) bearing halogen-functionalized aromatic isocyanide ligands were synthesized. The compounds were characterized by atomic emission spectroscopy (Cu), IR, 1H NMR spectroscopy and high-resolution mass spectrometry. The structure of nine compounds was determined by X-ray diffraction. Structural studies allow to reveal that the supramolecular structure of the complexes is based on weak C–H···X (X = Cl, Br, I) interactions and π-stacking of the aromatic rings of isocyanide ligands.

AB - Abstract: Eleven copper(I) halide complexes [CuX(CNR)3] (X = Cl, Br; R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2,6-Br2, C6H3-2-Br-6-Me; X = I, R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2-Br-6-Me) bearing halogen-functionalized aromatic isocyanide ligands were synthesized. The compounds were characterized by atomic emission spectroscopy (Cu), IR, 1H NMR spectroscopy and high-resolution mass spectrometry. The structure of nine compounds was determined by X-ray diffraction. Structural studies allow to reveal that the supramolecular structure of the complexes is based on weak C–H···X (X = Cl, Br, I) interactions and π-stacking of the aromatic rings of isocyanide ligands.

KW - X-ray diffraction

KW - copper(I) complexes

KW - isocyanides

KW - noncovalent interactions

UR - https://www.mendeley.com/catalogue/12e4f8f9-4561-3879-aeac-62ca1219a3db/

U2 - 10.1134/S1070363224070107

DO - 10.1134/S1070363224070107

M3 - Article

VL - 94

SP - 1682

EP - 1688

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 7

ER -

ID: 126138925