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Synthesis and structural characterization of two novel heterometallic clusters : [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]. / Koshevoy, Igor O.; Grachova, Elena V.; Tunik, Sergey P.; Haukka, Matti; Pakkanen, Tapani A.; Heaton, Brian T.; Iggo, Jonathan A.; Podkorytov, Ivan S.

In: Dalton Transactions, No. 22, 21.11.2004, p. 3893-3899.

Research output: Contribution to journal › Article › peer-review

Harvard

Koshevoy, IO, Grachova, EV, Tunik, SP, Haukka, M, Pakkanen, TA, Heaton, BT, Iggo, JA & Podkorytov, IS 2004, 'Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]', Dalton Transactions, no. 22, pp. 3893-3899. https://doi.org/10.1039/b410216a

APA

Koshevoy, I. O., Grachova, E. V., Tunik, S. P., Haukka, M., Pakkanen, T. A., Heaton, B. T., Iggo, J. A., & Podkorytov, I. S. (2004). Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]. Dalton Transactions, (22), 3893-3899. https://doi.org/10.1039/b410216a

Vancouver

Koshevoy IO, Grachova EV, Tunik SP, Haukka M, Pakkanen TA, Heaton BT et al. Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]. Dalton Transactions. 2004 Nov 21;(22):3893-3899. https://doi.org/10.1039/b410216a

Author

Koshevoy, Igor O. ; Grachova, Elena V. ; Tunik, Sergey P. ; Haukka, Matti ; Pakkanen, Tapani A. ; Heaton, Brian T. ; Iggo, Jonathan A. ; Podkorytov, Ivan S. / Synthesis and structural characterization of two novel heterometallic clusters : [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]. In: Dalton Transactions. 2004 ; No. 22. pp. 3893-3899.

BibTeX

@article{7d3a3d9e66ce48068be29e0077a2118e,
title = "Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]",
abstract = "Two novel heterometallic octahedral clusters [Rh4Pt 2(CO)11,(dppm)2] (1) and [Ru2Rh 2Pt2(CO)12(dppm)] (2) were synthesized by the reaction of [Rh2Pt2(CO)6(dppm)2] with [Rh6(CO)14(NCMe)2] and Ru 3(CO)12, respectively. Solid state structures of 1 and 2 have been established by a single crystal X-ray diffraction study. Two dppm ligands in 1 are bonded to one platinum and three rhodium atoms, which form an equatorial plane of the Rh4Pt2 octahedron. Two rhodium and two platinum atoms bound to the diphosphine ligands in 2 are nonplanar to give an octahedral C2 symmetric Ru2Rh2Pt 2(dppm)2 framework. The 31P NMR investigation of 1 and 2 (ID, 31P COSY, 31P-{103Rh} HMQC) and simulation of 1D spectral patterns showed that in both clusters the structures of the M6(PP)2 fragments found in the solid state are maintained in solution.",
author = "Koshevoy, {Igor O.} and Grachova, {Elena V.} and Tunik, {Sergey P.} and Matti Haukka and Pakkanen, {Tapani A.} and Heaton, {Brian T.} and Iggo, {Jonathan A.} and Podkorytov, {Ivan S.}",
year = "2004",
month = nov,
day = "21",
doi = "10.1039/b410216a",
language = "English",
pages = "3893--3899",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "22",

}

RIS

TY - JOUR

T1 - Synthesis and structural characterization of two novel heterometallic clusters

T2 - [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2]

AU - Koshevoy, Igor O.

AU - Grachova, Elena V.

AU - Tunik, Sergey P.

AU - Haukka, Matti

AU - Pakkanen, Tapani A.

AU - Heaton, Brian T.

AU - Iggo, Jonathan A.

AU - Podkorytov, Ivan S.

PY - 2004/11/21

Y1 - 2004/11/21

N2 - Two novel heterometallic octahedral clusters [Rh4Pt 2(CO)11,(dppm)2] (1) and [Ru2Rh 2Pt2(CO)12(dppm)] (2) were synthesized by the reaction of [Rh2Pt2(CO)6(dppm)2] with [Rh6(CO)14(NCMe)2] and Ru 3(CO)12, respectively. Solid state structures of 1 and 2 have been established by a single crystal X-ray diffraction study. Two dppm ligands in 1 are bonded to one platinum and three rhodium atoms, which form an equatorial plane of the Rh4Pt2 octahedron. Two rhodium and two platinum atoms bound to the diphosphine ligands in 2 are nonplanar to give an octahedral C2 symmetric Ru2Rh2Pt 2(dppm)2 framework. The 31P NMR investigation of 1 and 2 (ID, 31P COSY, 31P-{103Rh} HMQC) and simulation of 1D spectral patterns showed that in both clusters the structures of the M6(PP)2 fragments found in the solid state are maintained in solution.

AB - Two novel heterometallic octahedral clusters [Rh4Pt 2(CO)11,(dppm)2] (1) and [Ru2Rh 2Pt2(CO)12(dppm)] (2) were synthesized by the reaction of [Rh2Pt2(CO)6(dppm)2] with [Rh6(CO)14(NCMe)2] and Ru 3(CO)12, respectively. Solid state structures of 1 and 2 have been established by a single crystal X-ray diffraction study. Two dppm ligands in 1 are bonded to one platinum and three rhodium atoms, which form an equatorial plane of the Rh4Pt2 octahedron. Two rhodium and two platinum atoms bound to the diphosphine ligands in 2 are nonplanar to give an octahedral C2 symmetric Ru2Rh2Pt 2(dppm)2 framework. The 31P NMR investigation of 1 and 2 (ID, 31P COSY, 31P-{103Rh} HMQC) and simulation of 1D spectral patterns showed that in both clusters the structures of the M6(PP)2 fragments found in the solid state are maintained in solution.

UR - http://www.scopus.com/inward/record.url?scp=10644258884&partnerID=8YFLogxK

U2 - 10.1039/b410216a

DO - 10.1039/b410216a

M3 - Article

SP - 3893

EP - 3899

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 22

ER -

ID: 5114851