Synthesis and properties of 99Tc(I) and 99m Tc(I) hexacarbonyl in aqueous solutions

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Synthesis and properties of ⁹⁹Tc(I) and ^99m Tc(I) hexacarbonyl in aqueous solutions. / Miroslavov, A. E.; Sidorenko, G. V.; Lumpov, A. A.; Mikhalev, V. A.; Suglobov, D. N.

In: Radiochemistry, Vol. 51, No. 2, 04.2009, p. 124-131.

Research output: Contribution to journal › Article › peer-review

Author

Miroslavov, A. E. ; Sidorenko, G. V. ; Lumpov, A. A. ; Mikhalev, V. A. ; Suglobov, D. N. / Synthesis and properties of ⁹⁹Tc(I) and ^99m Tc(I) hexacarbonyl in aqueous solutions. In: Radiochemistry. 2009 ; Vol. 51, No. 2. pp. 124-131.

BibTeX

@article{499ba6615f8a46a1bfe4b3afd24c71ac,

title = "Synthesis and properties of 99Tc(I) and 99m Tc(I) hexacarbonyl in aqueous solutions",

abstract = "A procedure was developed for preparing Tc(CO)6ClO4 by carbonylation of a solution of technetium(I) tricarbonyltriaqua complex in 2 M HClO4 in a pressure vessel at 100-170°C and CO pressure of 150 atm. The hexacarbonyltechnetium cation in solution was characterized by IR and 99Tc NMR spectroscopy, and also by high-performance liquid chromatography (HPLC). The effect of particular acid and of synthesis conditions on the yield of the hexacarbonyltechnetium cation was examined, and the stability of this cation in aqueous solutions was evaluated. Conditions were found for preparing an aqueous solution containing 99m Tc(CO) 6 + .",

author = "Miroslavov, {A. E.} and Sidorenko, {G. V.} and Lumpov, {A. A.} and Mikhalev, {V. A.} and Suglobov, {D. N.}",

year = "2009",

month = apr,

doi = "10.1134/S1066362209020040",

language = "English",

volume = "51",

pages = "124--131",

journal = "Radiochemistry",

issn = "1066-3622",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "2",

}

RIS

TY - JOUR

T1 - Synthesis and properties of 99Tc(I) and 99m Tc(I) hexacarbonyl in aqueous solutions

AU - Miroslavov, A. E.

AU - Sidorenko, G. V.

AU - Lumpov, A. A.

AU - Mikhalev, V. A.

AU - Suglobov, D. N.

PY - 2009/4

Y1 - 2009/4

N2 - A procedure was developed for preparing Tc(CO)6ClO4 by carbonylation of a solution of technetium(I) tricarbonyltriaqua complex in 2 M HClO4 in a pressure vessel at 100-170°C and CO pressure of 150 atm. The hexacarbonyltechnetium cation in solution was characterized by IR and 99Tc NMR spectroscopy, and also by high-performance liquid chromatography (HPLC). The effect of particular acid and of synthesis conditions on the yield of the hexacarbonyltechnetium cation was examined, and the stability of this cation in aqueous solutions was evaluated. Conditions were found for preparing an aqueous solution containing 99m Tc(CO) 6 + .

AB - A procedure was developed for preparing Tc(CO)6ClO4 by carbonylation of a solution of technetium(I) tricarbonyltriaqua complex in 2 M HClO4 in a pressure vessel at 100-170°C and CO pressure of 150 atm. The hexacarbonyltechnetium cation in solution was characterized by IR and 99Tc NMR spectroscopy, and also by high-performance liquid chromatography (HPLC). The effect of particular acid and of synthesis conditions on the yield of the hexacarbonyltechnetium cation was examined, and the stability of this cation in aqueous solutions was evaluated. Conditions were found for preparing an aqueous solution containing 99m Tc(CO) 6 + .

UR - http://www.scopus.com/inward/record.url?scp=65649085285&partnerID=8YFLogxK

U2 - 10.1134/S1066362209020040

DO - 10.1134/S1066362209020040

M3 - Article

AN - SCOPUS:65649085285

VL - 51

SP - 124

EP - 131

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 2

ER -

ID: 76835472