Standard

Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+). / Konakov, V. G.; Kurapova, O. Yu; Borisova, N. V.; Golubev, S.N.; Ushakov, V. M.; Koroleva, E. V.; Archakov, I. Yu.

In: Journal of Sol-Gel Science and Technology, Vol. 82, No. 1, 01.04.2017, p. 214-223.

Research output: Contribution to journal › Article › peer-review

Harvard

Konakov, VG, Kurapova, OY, Borisova, NV, Golubev, SN, Ushakov, VM, Koroleva, EV & Archakov, IY 2017, 'Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+)', Journal of Sol-Gel Science and Technology, vol. 82, no. 1, pp. 214-223. https://doi.org/10.1007/s10971-016-4278-7, https://doi.org/10.1007/s10971-016-4278-7

APA

Konakov, V. G., Kurapova, O. Y., Borisova, N. V., Golubev, S. N., Ushakov, V. M., Koroleva, E. V., & Archakov, I. Y. (2017). Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+). Journal of Sol-Gel Science and Technology, 82(1), 214-223. https://doi.org/10.1007/s10971-016-4278-7, https://doi.org/10.1007/s10971-016-4278-7

Vancouver

Konakov VG, Kurapova OY, Borisova NV, Golubev SN, Ushakov VM, Koroleva EV et al. Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+). Journal of Sol-Gel Science and Technology. 2017 Apr 1;82(1):214-223. https://doi.org/10.1007/s10971-016-4278-7, https://doi.org/10.1007/s10971-016-4278-7

Author

Konakov, V. G. ; Kurapova, O. Yu ; Borisova, N. V. ; Golubev, S.N. ; Ushakov, V. M. ; Koroleva, E. V. ; Archakov, I. Yu. / Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+). In: Journal of Sol-Gel Science and Technology. 2017 ; Vol. 82, No. 1. pp. 214-223.

BibTeX

@article{5410cabbc4d54e6c99c2ca2e13585cb2,
title = "Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+)",
abstract = "Abstract: The paper reports the synthesis and the investigation of the phase formation in MxOy–ZrO2 nanosized systems the temperature range 360–850 °С, performed via simultaneous thermal analysis, X-ray diffraction analysis and particle size distribution analysis. Nanosized MO-ZrO2 precursors with MO content 5–10 mol.% and Bi2O3–ZrO2 precursors with Bi2O3 content 5–14 mol.% were obtained by reversed co-precipitation from diluted salts solutions with following drying under exceeded pressure. In contrast to microsized systems,nanosized powders exhibit exothermic effects corresponding to crystallization at 360–570 °С in DSC curves. Metastable cubic zirconia solid solutions are present after annealing for all zirconia based precursors studied phase evolution study innanosized MxOy–ZrO2 systems (M = Zn2+, Cd2+, Pb2+, Bi3+) except 10PbO–90ZrO2 composition. Cubic zirconia solid solution with no admixture of monoclinic phase is formed only in case of 14Bi2O3–96ZrO2. The stability of cubic solid solutions formed in time and temperature range was studied by X-ray diffraction. Crystalline size estimated from Scherrer{\textquoteright}s equation is 17–25 nm. The main agglomerate size calculated from particle size distribution analysis lie in the range 234–590 nm. Nanocrystallinity and high dispersity of powders favor phase stability of cubic solid solutions formed. Graphical Abstract: [InlineMediaObject not available: see fulltext.]",
keywords = "Co-precipitation, Crystallization, Cubic zirconia solid solutions, Nanopowders, Ostwald step rule, Phase formation",
author = "Konakov, {V. G.} and Kurapova, {O. Yu} and Borisova, {N. V.} and S.N. Golubev and Ushakov, {V. M.} and Koroleva, {E. V.} and Archakov, {I. Yu}",
year = "2017",
month = apr,
day = "1",
doi = "10.1007/s10971-016-4278-7",
language = "English",
volume = "82",
pages = "214--223",
journal = "Journal of Sol-Gel Science and Technology",
issn = "0928-0707",
publisher = "Springer Nature",
number = "1",

}

RIS

TY - JOUR

T1 - Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+)

AU - Konakov, V. G.

AU - Kurapova, O. Yu

AU - Borisova, N. V.

AU - Golubev, S.N.

AU - Ushakov, V. M.

AU - Koroleva, E. V.

AU - Archakov, I. Yu

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Abstract: The paper reports the synthesis and the investigation of the phase formation in MxOy–ZrO2 nanosized systems the temperature range 360–850 °С, performed via simultaneous thermal analysis, X-ray diffraction analysis and particle size distribution analysis. Nanosized MO-ZrO2 precursors with MO content 5–10 mol.% and Bi2O3–ZrO2 precursors with Bi2O3 content 5–14 mol.% were obtained by reversed co-precipitation from diluted salts solutions with following drying under exceeded pressure. In contrast to microsized systems,nanosized powders exhibit exothermic effects corresponding to crystallization at 360–570 °С in DSC curves. Metastable cubic zirconia solid solutions are present after annealing for all zirconia based precursors studied phase evolution study innanosized MxOy–ZrO2 systems (M = Zn2+, Cd2+, Pb2+, Bi3+) except 10PbO–90ZrO2 composition. Cubic zirconia solid solution with no admixture of monoclinic phase is formed only in case of 14Bi2O3–96ZrO2. The stability of cubic solid solutions formed in time and temperature range was studied by X-ray diffraction. Crystalline size estimated from Scherrer’s equation is 17–25 nm. The main agglomerate size calculated from particle size distribution analysis lie in the range 234–590 nm. Nanocrystallinity and high dispersity of powders favor phase stability of cubic solid solutions formed. Graphical Abstract: [InlineMediaObject not available: see fulltext.]

AB - Abstract: The paper reports the synthesis and the investigation of the phase formation in MxOy–ZrO2 nanosized systems the temperature range 360–850 °С, performed via simultaneous thermal analysis, X-ray diffraction analysis and particle size distribution analysis. Nanosized MO-ZrO2 precursors with MO content 5–10 mol.% and Bi2O3–ZrO2 precursors with Bi2O3 content 5–14 mol.% were obtained by reversed co-precipitation from diluted salts solutions with following drying under exceeded pressure. In contrast to microsized systems,nanosized powders exhibit exothermic effects corresponding to crystallization at 360–570 °С in DSC curves. Metastable cubic zirconia solid solutions are present after annealing for all zirconia based precursors studied phase evolution study innanosized MxOy–ZrO2 systems (M = Zn2+, Cd2+, Pb2+, Bi3+) except 10PbO–90ZrO2 composition. Cubic zirconia solid solution with no admixture of monoclinic phase is formed only in case of 14Bi2O3–96ZrO2. The stability of cubic solid solutions formed in time and temperature range was studied by X-ray diffraction. Crystalline size estimated from Scherrer’s equation is 17–25 nm. The main agglomerate size calculated from particle size distribution analysis lie in the range 234–590 nm. Nanocrystallinity and high dispersity of powders favor phase stability of cubic solid solutions formed. Graphical Abstract: [InlineMediaObject not available: see fulltext.]

KW - Co-precipitation

KW - Crystallization

KW - Cubic zirconia solid solutions

KW - Nanopowders

KW - Ostwald step rule

KW - Phase formation

UR - http://www.scopus.com/inward/record.url?scp=85006084805&partnerID=8YFLogxK

U2 - 10.1007/s10971-016-4278-7

DO - 10.1007/s10971-016-4278-7

M3 - Article

AN - SCOPUS:85006084805

VL - 82

SP - 214

EP - 223

JO - Journal of Sol-Gel Science and Technology

JF - Journal of Sol-Gel Science and Technology

SN - 0928-0707

IS - 1

ER -

ID: 35346420