Research output: Contribution to journal › Article › peer-review
Synthesis and Molecular Properties of New Side-Chain Liquid Crystalline Polymers Based on the Baylis-Hillman Reaction. / Lavrenko, Peter; Yevlampieva, Natalia; Okatova, Olga; Polushin, Sergei; Lacey, David; Hall, Alan W.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 332, 01.01.1999, p. 505-512.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and Molecular Properties of New Side-Chain Liquid Crystalline Polymers Based on the Baylis-Hillman Reaction
AU - Lavrenko, Peter
AU - Yevlampieva, Natalia
AU - Okatova, Olga
AU - Polushin, Sergei
AU - Lacey, David
AU - Hall, Alan W.
PY - 1999/1/1
Y1 - 1999/1/1
N2 - A new methodology has been employed in synthesis of two side-chain liquid-crystalline polymers with cyanobiphenylene mesogenic groups and variation of -CN, -COCH3 and -OH groups displacement in the backbone surrounding. Hydrodynamic and electrooptical (the Kerr effect) methods were used to study their molecular properties in solution in benzene and chloroform. Electrooptical properties of polymers are compared with the same ones of homologous series of alkoxycyanobiphenylenes as the model compounds of the polymer mesogenic groups. Different mobility of the side-chain mesogenic groups in polymers under investigation was observed and related to the chemical and dipole structure.
AB - A new methodology has been employed in synthesis of two side-chain liquid-crystalline polymers with cyanobiphenylene mesogenic groups and variation of -CN, -COCH3 and -OH groups displacement in the backbone surrounding. Hydrodynamic and electrooptical (the Kerr effect) methods were used to study their molecular properties in solution in benzene and chloroform. Electrooptical properties of polymers are compared with the same ones of homologous series of alkoxycyanobiphenylenes as the model compounds of the polymer mesogenic groups. Different mobility of the side-chain mesogenic groups in polymers under investigation was observed and related to the chemical and dipole structure.
KW - Electro-optics
KW - LC polymers
KW - Mesogens mobility
KW - Stereotacticity
UR - http://www.scopus.com/inward/record.url?scp=0041726921&partnerID=8YFLogxK
U2 - 10.1080/10587259908023796
DO - 10.1080/10587259908023796
M3 - Article
AN - SCOPUS:0041726921
VL - 332
SP - 505
EP - 512
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
SN - 1542-1406
ER -
ID: 142923116