Research output: Contribution to journal › Article › peer-review
Synthesis and luminescent properties of functionalized polynorbornenes with boron-containing fragments in side chains. / Rozhkov, A. V.; Basova, G. V.; Korshunov, A. O.; Bochkarev, L. N.; Glukhova, T. A.; Il´ichev, V. A.
In: Russian Chemical Bulletin, Vol. 64, No. 8, 01.08.2015, p. 1949-1954.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and luminescent properties of functionalized polynorbornenes with boron-containing fragments in side chains
AU - Rozhkov, A. V.
AU - Basova, G. V.
AU - Korshunov, A. O.
AU - Bochkarev, L. N.
AU - Glukhova, T. A.
AU - Il´ichev, V. A.
PY - 2015/8/1
Y1 - 2015/8/1
N2 - New norbornene monomer, viz., 5-[(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)methyl]-8-[(dimesitylboryl)oxy]quinoline (1), was synthesized. The copolymers based on monomer 1 and carbazole-containing norbornene derivatives were synthesized by ring-opening metathesis polymerization. The photoluminescent (PL) and electroluminescent (EL) properties of the synthesized polymeric products were studied. The copolymers revealed the green EL with a maximum luminance of 146 cd m–2. The dependences between the PL and EL efficiencies of the polymers and their structures were determined.
AB - New norbornene monomer, viz., 5-[(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)methyl]-8-[(dimesitylboryl)oxy]quinoline (1), was synthesized. The copolymers based on monomer 1 and carbazole-containing norbornene derivatives were synthesized by ring-opening metathesis polymerization. The photoluminescent (PL) and electroluminescent (EL) properties of the synthesized polymeric products were studied. The copolymers revealed the green EL with a maximum luminance of 146 cd m–2. The dependences between the PL and EL efficiencies of the polymers and their structures were determined.
KW - boron
KW - carbazole
KW - electroluminescence
KW - luminescent polymers
KW - metathesis polymerization
KW - photo-luminescence
UR - http://www.scopus.com/inward/record.url?scp=84964975007&partnerID=8YFLogxK
U2 - 10.1007/s11172-015-1098-9
DO - 10.1007/s11172-015-1098-9
M3 - Article
AN - SCOPUS:84964975007
VL - 64
SP - 1949
EP - 1954
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 8
ER -
ID: 39928346