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In the present work the electrical properties of (1 - x)Ce0.8Gd0.2O2 - δ + xTiO2 (x = 0-0.06) synthesized by the standard ceramic technology were investigated, in a wide range of oxygen partial pressures (0.21-10- 20atm at 900 °C) and temperatures (600-900 °C), both in air and H2 + 3%H2O atmosphere. It was found, that only the introduction of above 1 mol% TiO2 decreases the sintering temperature of Ce0.8Gd0.2O2 - δ. The values of total electrical conductivity do not change significantly with the content of the sintering aid up to 3 mol%, while the activation energy of total conductivity in air decreases considerably with the introduction of TiO2 into Ce0.8Gd0.2O2 - δ from 87 to 67 kJ/mol; however, it is independent of x up to 0.03. The dependence of the total conductivity on the oxygen partial pressure is characterized by three regions. In the intermediate region (10- 10-10- 14) the conductivity behavior is described according to the oxygen vacancy model. The n-type conductivity region curve of Ce0.8Gd0.2O2 - δ is fitted to a -1/5 slope. The increase of TiO2 content leads to the slope increase at - 1/6, - 1/8 and - 1/9 for 1, 2 and 3 mol% TiO2, respectively, due to the trapping of electrons by Ti4+. 1 mol% doping increases the electrolytic region of Ce0.8Gd0.2O2 - δ from 10- 10 to 10- 13atm. Finally, the optimal content of TiO2 from the viewpoint of sintering and electrical properties was found to be 2 mol%.
Original language | English |
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Pages (from-to) | 1557-1561 |
Number of pages | 5 |
Journal | Solid State Ionics |
Volume | 179 |
Issue number | 27-32 |
DOIs | |
State | Published - 30 Sep 2008 |
ID: 85232550