Research output: Contribution to journal › Article › peer-review
Synthesis and electrochemical properties of poly(3,4-dihydroxystyrene) and its composites with conducting polymers. / Lukyanov, D.A.; Apraksin, R.V.; Yankin, A.N.; Vlasov, P.S.; Levin, O.V.; Tolstopjatova, E.G.; Kondratiev, V.V.
In: Synthetic Metals, Vol. 256, 116151, 01.10.2019.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and electrochemical properties of poly(3,4-dihydroxystyrene) and its composites with conducting polymers
AU - Lukyanov, D.A.
AU - Apraksin, R.V.
AU - Yankin, A.N.
AU - Vlasov, P.S.
AU - Levin, O.V.
AU - Tolstopjatova, E.G.
AU - Kondratiev, V.V.
N1 - Lukyanov, D. A., Apraksin, R. V., Yankin, A. N., Vlasov, P. S., Levin, O. V., Tolstopjatova, E. G., & Kondratiev, V. V. (2019). Synthesis and electrochemical properties of poly(3,4-dihydroxystyrene) and its composites with conducting polymers. Synthetic Metals, 256, 116151. https://doi.org/10.1016/j.synthmet.2019.116151
PY - 2019/10/1
Y1 - 2019/10/1
N2 - The present study reports electrochemical performance of electrode materials based on poly(3,4-dihydroxystyrene) (PDHS) and its composites with conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT), deposited on glassy carbon electrodes, in diluted sulfuric acid. Poly(3,4-dihydroxystyrene), bearing redox active hydroquinone groups, was employed to the first time as an electrode material in combination with carbon, binder and conducting polymer. It was found that this quinone-based composite exhibits moderate electrochemical characteristics with specific capacity of about 50–54 mA h g −1. The comparison of rate constants obtained for GC/PDHS and GC/PEDOT/PDHS electrodes confirms the catalytic effect of conducting polymer PEDOT on the redox transformation of PDHS.
AB - The present study reports electrochemical performance of electrode materials based on poly(3,4-dihydroxystyrene) (PDHS) and its composites with conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT), deposited on glassy carbon electrodes, in diluted sulfuric acid. Poly(3,4-dihydroxystyrene), bearing redox active hydroquinone groups, was employed to the first time as an electrode material in combination with carbon, binder and conducting polymer. It was found that this quinone-based composite exhibits moderate electrochemical characteristics with specific capacity of about 50–54 mA h g −1. The comparison of rate constants obtained for GC/PDHS and GC/PEDOT/PDHS electrodes confirms the catalytic effect of conducting polymer PEDOT on the redox transformation of PDHS.
KW - Composite materials
KW - Conducting polymers
KW - Cyclic voltammetry
KW - Electrochemical capacitors
KW - Poly(3,4-dihydroxystyrene)
KW - Poly-3,4-ethylenedioxythiophene
UR - http://www.scopus.com/inward/record.url?scp=85071365339&partnerID=8YFLogxK
UR - https://linkinghub.elsevier.com/retrieve/pii/S0379677919304552
UR - http://www.mendeley.com/research/synthesis-electrochemical-properties-poly34dihydroxystyrene-composites-conducting-polymers
U2 - https://doi.org/10.1016/j.synthmet.2019.116151
DO - https://doi.org/10.1016/j.synthmet.2019.116151
M3 - Article
VL - 256
JO - Synthetic Metals
JF - Synthetic Metals
SN - 0379-6779
M1 - 116151
ER -
ID: 45496156