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Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite. / Борисов, Артем Сергеевич; Сийдра, Олег Иоханнесович; Чаркин, Дмитрий Олегович; Николаевич, Глеб; Байкина, Анна Сергеевна; Назарчук, Евгений Васильевич.

In: Journal of Structural Chemistry, Vol. 65, No. 12, 12.2024, p. 2371-2383.

Research output: Contribution to journal › Article › peer-review

Harvard

Борисов, АС, Сийдра, ОИ, Чаркин, ДО, Николаевич, Г, Байкина, АС & Назарчук, ЕВ 2024, 'Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite', Journal of Structural Chemistry, vol. 65, no. 12, pp. 2371-2383. https://doi.org/10.1134/s0022476624120023

APA

Борисов, А. С., Сийдра, О. И., Чаркин, Д. О., Николаевич, Г., Байкина, А. С., & Назарчук, Е. В. (2024). Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite. Journal of Structural Chemistry, 65(12), 2371-2383. https://doi.org/10.1134/s0022476624120023

Vancouver

Борисов АС, Сийдра ОИ, Чаркин ДО, Николаевич Г, Байкина АС, Назарчук ЕВ. Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite. Journal of Structural Chemistry. 2024 Dec;65(12):2371-2383. https://doi.org/10.1134/s0022476624120023

Author

Борисов, Артем Сергеевич ; Сийдра, Олег Иоханнесович ; Чаркин, Дмитрий Олегович ; Николаевич, Глеб ; Байкина, Анна Сергеевна ; Назарчук, Евгений Васильевич. / Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 12. pp. 2371-2383.

BibTeX

@article{24f41e22929f467481df767bed05ca3a,
title = "Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite",
abstract = "Abstract: We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu6O2(MoO4)3(SO4). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu6O2(MoO4)3(SO4) is monoclinic, space group P21/m, a = 7.5208(4) {\AA}, b = 6.8602(3) {\AA}, c = 14.0019(7) {\AA}, β = 93.471(5)°, V = 721.09(6) {\AA}3, R1 = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu3]4+ chains and MoO4 and SO4 tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn3O(SO4)2 and vergasovaite Cu3O(MoO4)(SO4). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed",
keywords = "copper, glikinite, molybdates, oxo-centered complexes, sulfates, vergasovaite",
author = "Борисов, {Артем Сергеевич} and Сийдра, {Олег Иоханнесович} and Чаркин, {Дмитрий Олегович} and Глеб Николаевич and Байкина, {Анна Сергеевна} and Назарчук, {Евгений Васильевич}",
year = "2024",
month = dec,
doi = "10.1134/s0022476624120023",
language = "English",
volume = "65",
pages = "2371--2383",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer Nature",
number = "12",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of Cu6O2(MoO4)3(SO4), a new copper oxysulfate-molybdate, structurally related to vergasovaite and glikinite

AU - Борисов, Артем Сергеевич

AU - Сийдра, Олег Иоханнесович

AU - Чаркин, Дмитрий Олегович

AU - Николаевич, Глеб

AU - Байкина, Анна Сергеевна

AU - Назарчук, Евгений Васильевич

PY - 2024/12

Y1 - 2024/12

N2 - Abstract: We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu6O2(MoO4)3(SO4). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu6O2(MoO4)3(SO4) is monoclinic, space group P21/m, a = 7.5208(4) Å, b = 6.8602(3) Å, c = 14.0019(7) Å, β = 93.471(5)°, V = 721.09(6) Å3, R1 = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu3]4+ chains and MoO4 and SO4 tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn3O(SO4)2 and vergasovaite Cu3O(MoO4)(SO4). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed

AB - Abstract: We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu6O2(MoO4)3(SO4). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu6O2(MoO4)3(SO4) is monoclinic, space group P21/m, a = 7.5208(4) Å, b = 6.8602(3) Å, c = 14.0019(7) Å, β = 93.471(5)°, V = 721.09(6) Å3, R1 = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu3]4+ chains and MoO4 and SO4 tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn3O(SO4)2 and vergasovaite Cu3O(MoO4)(SO4). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed

KW - copper

KW - glikinite

KW - molybdates

KW - oxo-centered complexes

KW - sulfates

KW - vergasovaite

UR - https://link.springer.com/article/10.1134/S0022476624120023

UR - https://www.mendeley.com/catalogue/5a870535-da48-3a9e-9be8-345e5d0fc22e/

U2 - 10.1134/s0022476624120023

DO - 10.1134/s0022476624120023

M3 - Article

VL - 65

SP - 2371

EP - 2383

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 132249339