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Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines. / Kondratenko, Yulia A.; Ignatyev, Igor S.; Lezov, Denis V.; Arsent'ev, Maxim Y.; Zolotarev, Andrey A.; Ugolkov, Valerii L.; Antuganov, Dmitrii; Kochina, Tatyana A.

In: Journal of Organometallic Chemistry, Vol. 958, 122188, 15.01.2022, p. 122188.

Research output: Contribution to journal › Article › peer-review

Harvard

Kondratenko, YA, Ignatyev, IS, Lezov, DV, Arsent'ev, MY, Zolotarev, AA, Ugolkov, VL, Antuganov, D & Kochina, TA 2022, 'Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines', Journal of Organometallic Chemistry, vol. 958, 122188, pp. 122188. https://doi.org/10.1016/j.jorganchem.2021.122188

APA

Kondratenko, Y. A., Ignatyev, I. S., Lezov, D. V., Arsent'ev, M. Y., Zolotarev, A. A., Ugolkov, V. L., Antuganov, D., & Kochina, T. A. (2022). Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines. Journal of Organometallic Chemistry, 958, 122188. [122188]. https://doi.org/10.1016/j.jorganchem.2021.122188

Vancouver

Kondratenko YA, Ignatyev IS, Lezov DV, Arsent'ev MY, Zolotarev AA, Ugolkov VL et al. Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines. Journal of Organometallic Chemistry. 2022 Jan 15;958:122188. 122188. https://doi.org/10.1016/j.jorganchem.2021.122188

Author

Kondratenko, Yulia A. ; Ignatyev, Igor S. ; Lezov, Denis V. ; Arsent'ev, Maxim Y. ; Zolotarev, Andrey A. ; Ugolkov, Valerii L. ; Antuganov, Dmitrii ; Kochina, Tatyana A. / Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines. In: Journal of Organometallic Chemistry. 2022 ; Vol. 958. pp. 122188.

BibTeX

@article{6d967073374f480c86a319d35dae39ef,
title = "Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines",
abstract = "New germatranes 1–3 were synthesized by the interaction of germanium oxide with N-(2-hydroxyethyl)ethylenediamine (complex 1), N,N,N'N{\textquoteright}-tetrakis(2-hydroxyethyl)ethylenediamine (complex 2) and N,N,N'N{\textquoteright}-tetrakis(2-hydroxypropyl)ethylenediamine (complex 3). Their composition was confirmed by the data of elemental analysis, IR, UV/Vis and NMR spectroscopy. The thermal behavior of synthesized complexes 1–3 was studied in the temperature range 40–600 °C. The crystal structure of compound 2 was determined using single-crystal X-ray diffraction. The Hirschfeld surface analysis was performed to quantify the intermolecular contacts present within the crystal structure of complex 2. The equilibrium structures of the synthesized compounds 1–3 were calculated using DFT methods.",
keywords = "DFT calculations, Germatranes, Hirschfeld surface analysis, Hydroxyalkylethylenediamines, Hypercoordinated germanium, X-ray crystal structure, THERMOCHEMISTRY, BIOLOGICAL EVALUATION, &nbsp, GERMATRANOL, SILATRANE",
author = "Kondratenko, {Yulia A.} and Ignatyev, {Igor S.} and Lezov, {Denis V.} and Arsent'ev, {Maxim Y.} and Zolotarev, {Andrey A.} and Ugolkov, {Valerii L.} and Dmitrii Antuganov and Kochina, {Tatyana A.}",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",
year = "2022",
month = jan,
day = "15",
doi = "10.1016/j.jorganchem.2021.122188",
language = "English",
volume = "958",
pages = "122188",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and characterization of hypercoordinated germanium complexes with hydroxyalkylethylenediamines

AU - Kondratenko, Yulia A.

AU - Ignatyev, Igor S.

AU - Lezov, Denis V.

AU - Arsent'ev, Maxim Y.

AU - Zolotarev, Andrey A.

AU - Ugolkov, Valerii L.

AU - Antuganov, Dmitrii

AU - Kochina, Tatyana A.

N1 - Publisher Copyright: © 2021 Elsevier B.V.

PY - 2022/1/15

Y1 - 2022/1/15

N2 - New germatranes 1–3 were synthesized by the interaction of germanium oxide with N-(2-hydroxyethyl)ethylenediamine (complex 1), N,N,N'N’-tetrakis(2-hydroxyethyl)ethylenediamine (complex 2) and N,N,N'N’-tetrakis(2-hydroxypropyl)ethylenediamine (complex 3). Their composition was confirmed by the data of elemental analysis, IR, UV/Vis and NMR spectroscopy. The thermal behavior of synthesized complexes 1–3 was studied in the temperature range 40–600 °C. The crystal structure of compound 2 was determined using single-crystal X-ray diffraction. The Hirschfeld surface analysis was performed to quantify the intermolecular contacts present within the crystal structure of complex 2. The equilibrium structures of the synthesized compounds 1–3 were calculated using DFT methods.

AB - New germatranes 1–3 were synthesized by the interaction of germanium oxide with N-(2-hydroxyethyl)ethylenediamine (complex 1), N,N,N'N’-tetrakis(2-hydroxyethyl)ethylenediamine (complex 2) and N,N,N'N’-tetrakis(2-hydroxypropyl)ethylenediamine (complex 3). Their composition was confirmed by the data of elemental analysis, IR, UV/Vis and NMR spectroscopy. The thermal behavior of synthesized complexes 1–3 was studied in the temperature range 40–600 °C. The crystal structure of compound 2 was determined using single-crystal X-ray diffraction. The Hirschfeld surface analysis was performed to quantify the intermolecular contacts present within the crystal structure of complex 2. The equilibrium structures of the synthesized compounds 1–3 were calculated using DFT methods.

KW - DFT calculations

KW - Germatranes

KW - Hirschfeld surface analysis

KW - Hydroxyalkylethylenediamines

KW - Hypercoordinated germanium

KW - X-ray crystal structure

KW - THERMOCHEMISTRY

KW - BIOLOGICAL EVALUATION

KW - &nbsp

KW - GERMATRANOL

KW - SILATRANE

UR - http://www.scopus.com/inward/record.url?scp=85120610795&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/a8fcd1ac-0191-3745-a789-24e895954ce2/

U2 - 10.1016/j.jorganchem.2021.122188

DO - 10.1016/j.jorganchem.2021.122188

M3 - Article

AN - SCOPUS:85120610795

VL - 958

SP - 122188

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

M1 - 122188

ER -

ID: 91120914