Standard

Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions. / Siidra, Oleg I.; Nazarchuk, Evgeny V.; Krivovichev, Sergey V.

In: Journal of Solid State Chemistry, Vol. 187, 03.2012, p. 286-290.

Research output: Contribution to journal › Article › peer-review

Harvard

Siidra, OI, Nazarchuk, EV & Krivovichev, SV 2012, 'Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions', Journal of Solid State Chemistry, vol. 187, pp. 286-290. https://doi.org/10.1016/j.jssc.2012.01.037

APA

Siidra, O. I., Nazarchuk, E. V., & Krivovichev, S. V. (2012). Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions. Journal of Solid State Chemistry, 187, 286-290. https://doi.org/10.1016/j.jssc.2012.01.037

Vancouver

Siidra OI, Nazarchuk EV, Krivovichev SV. Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions. Journal of Solid State Chemistry. 2012 Mar;187:286-290. https://doi.org/10.1016/j.jssc.2012.01.037

Author

Siidra, Oleg I. ; Nazarchuk, Evgeny V. ; Krivovichev, Sergey V. / Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions. In: Journal of Solid State Chemistry. 2012 ; Vol. 187. pp. 286-290.

BibTeX

@article{a00f957416394cd9bc787102711eb1c5,
title = "Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions",
abstract = "Single crystals of Cs 2(UO 2)(CrO 4) 2 and Rb 2(UO 2)(CrO 4) 2 were prepared by solid state reactions. The structures are based upon the [(UO 2)(CrO 4) 2] 2- chains. Within the chains, UrO 5 pentagonal bipyramids (Ur=uranyl) form Ur 2O 8 dimers, which are linked via CrO 4 tetrahedra into one-dimensional chains. The CrO 4 tetrahedra coordinate uranyl ions in both mono- and bidentate fashion, which is unusual for uranyl chromates. The bidentate coordination has a strong influence upon geometrical parameters of both U and Cr coordination polyhedra. The conformation of the chains in 1 and 2 is different due to the different size of the Cs and Rb cations.",
keywords = "Bidentate coordination, Single crystal X-ray diffraction, Structure determination, Uranyl chromates",
author = "Siidra, {Oleg I.} and Nazarchuk, {Evgeny V.} and Krivovichev, {Sergey V.}",
year = "2012",
month = mar,
doi = "10.1016/j.jssc.2012.01.037",
language = "English",
volume = "187",
pages = "286--290",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Syntheses and crystal structures of two novel alkaline uranyl chromates A 2(UO 2)(CrO 4) 2 (A=Rb, Cs) with bidentate coordination mode of uranyl ions by chromate anions

AU - Siidra, Oleg I.

AU - Nazarchuk, Evgeny V.

AU - Krivovichev, Sergey V.

PY - 2012/3

Y1 - 2012/3

N2 - Single crystals of Cs 2(UO 2)(CrO 4) 2 and Rb 2(UO 2)(CrO 4) 2 were prepared by solid state reactions. The structures are based upon the [(UO 2)(CrO 4) 2] 2- chains. Within the chains, UrO 5 pentagonal bipyramids (Ur=uranyl) form Ur 2O 8 dimers, which are linked via CrO 4 tetrahedra into one-dimensional chains. The CrO 4 tetrahedra coordinate uranyl ions in both mono- and bidentate fashion, which is unusual for uranyl chromates. The bidentate coordination has a strong influence upon geometrical parameters of both U and Cr coordination polyhedra. The conformation of the chains in 1 and 2 is different due to the different size of the Cs and Rb cations.

AB - Single crystals of Cs 2(UO 2)(CrO 4) 2 and Rb 2(UO 2)(CrO 4) 2 were prepared by solid state reactions. The structures are based upon the [(UO 2)(CrO 4) 2] 2- chains. Within the chains, UrO 5 pentagonal bipyramids (Ur=uranyl) form Ur 2O 8 dimers, which are linked via CrO 4 tetrahedra into one-dimensional chains. The CrO 4 tetrahedra coordinate uranyl ions in both mono- and bidentate fashion, which is unusual for uranyl chromates. The bidentate coordination has a strong influence upon geometrical parameters of both U and Cr coordination polyhedra. The conformation of the chains in 1 and 2 is different due to the different size of the Cs and Rb cations.

KW - Bidentate coordination

KW - Single crystal X-ray diffraction

KW - Structure determination

KW - Uranyl chromates

UR - http://www.scopus.com/inward/record.url?scp=84857232149&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2012.01.037

DO - 10.1016/j.jssc.2012.01.037

M3 - Article

AN - SCOPUS:84857232149

VL - 187

SP - 286

EP - 290

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

ID: 9145299