Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review
Synergistic mixtures of chlorinated cobalt dicarbollide and bidentate organophosphorus compounds for high-level waste reprocessing. / Babain, V. A.; Smirnov, I. V.; Antonov, N. G.; Luther, T. A.; Herbst, R. S.; Peterman, D. R.
Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy. 2003. p. 732-735 (Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review
}
TY - GEN
T1 - Synergistic mixtures of chlorinated cobalt dicarbollide and bidentate organophosphorus compounds for high-level waste reprocessing
AU - Babain, V. A.
AU - Smirnov, I. V.
AU - Antonov, N. G.
AU - Luther, T. A.
AU - Herbst, R. S.
AU - Peterman, D. R.
PY - 2003/12/1
Y1 - 2003/12/1
N2 - The mixtures of chlorinated cobalt dicarbollide (CCD) and bidentate organophosphorous compounds were used for high-level radioactive waste reprocessing. In the organic phase carbamoylphosphine oxides (CMPO) interacted both with nitric acid and the protonated form of CCD. It was confirmed by the signal displacement to lower fields in the 31P NMR spectra. The signals of the phenyl protons and methylene groups in 1H NMR spectra were also shifted. The results show that the most pronounced chemical shift occurred in the 31P NMR spectra, attributed to a strong interaction at the phosphoryl oxygen and indicating that the most useful spectra for studying other BNOPC was the 31P NMR spectra.
AB - The mixtures of chlorinated cobalt dicarbollide (CCD) and bidentate organophosphorous compounds were used for high-level radioactive waste reprocessing. In the organic phase carbamoylphosphine oxides (CMPO) interacted both with nitric acid and the protonated form of CCD. It was confirmed by the signal displacement to lower fields in the 31P NMR spectra. The signals of the phenyl protons and methylene groups in 1H NMR spectra were also shifted. The results show that the most pronounced chemical shift occurred in the 31P NMR spectra, attributed to a strong interaction at the phosphoryl oxygen and indicating that the most useful spectra for studying other BNOPC was the 31P NMR spectra.
UR - http://www.scopus.com/inward/record.url?scp=2642515680&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:2642515680
SN - 0894486772
T3 - Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy
SP - 732
EP - 735
BT - Global 2003
T2 - Global 2003: Atoms for Prosperity: Updating Eisenhower's Global Vision for Nuclear Energy
Y2 - 16 November 2003 through 20 November 2003
ER -
ID: 53580872