Introduction and history Paraffin films and other surface coatings have played a decisive role in the emergence and development of optical magnetometry. When alkali atoms in the vapor phase collide with the bare surface of a glass container, they disappear inside the glass and are replaced in the vapor phase by another atom with random spin orientation. With a mean free path of the dimensions of the cell (typically on the order of 1 to several cm), the collision frequency is much too high, 10⁴ s⁻¹, to maintain the substantial spin polarization required for practical applications. In order to prevent this detrimental effect, vapor cells include either an inert buffer gas [1–3] or an antirelaxation surface coating [4]. In the presence of a noble gas at a pressure from 10⁻² to a few atmospheres, the alkali atoms diffuse very slowly from the center of the cell to the glass walls, and their orientation is only very slightly affected by gas collisions. However, there are several advantages to the use of a surface coating instead of buffer gas. If the static magnetic field is not homogeneous, then resonance lines suffer from inhomogeneous broadening in the presence of the gas [5–7]. In addition, the optical pumping process is perturbed by the buffer gas [8, 9]: (i) it is more efficient at the center of the cell than near the uncoated walls, so that the atomic orientation is inhomogeneous inside the cell; (ii) the pump beam absorption line is broadened, and its profile varies with the distance from the entrance window. These effects are unfavorable for the production of alignment in the ground state.