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Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium. / Kodinzev, Ilia; Lobinsky, Artem; Tolstoy, Valeri.

State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018. ed. / Yuri Petrov; Oleg Vyvenko. American Institute of Physics, 2019. 030005 (AIP Conference Proceedings; Vol. 2064).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Harvard

Kodinzev, I, Lobinsky, A & Tolstoy, V 2019, Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium. in Y Petrov & O Vyvenko (eds), State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018., 030005, AIP Conference Proceedings, vol. 2064, American Institute of Physics, International Conference on State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018, Moscow, Russian Federation, 17/10/18. https://doi.org/10.1063/1.5087667

APA

Kodinzev, I., Lobinsky, A., & Tolstoy, V. (2019). Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium. In Y. Petrov, & O. Vyvenko (Eds.), State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018 [030005] (AIP Conference Proceedings; Vol. 2064). American Institute of Physics. https://doi.org/10.1063/1.5087667

Vancouver

Kodinzev I, Lobinsky A, Tolstoy V. Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium. In Petrov Y, Vyvenko O, editors, State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018. American Institute of Physics. 2019. 030005. (AIP Conference Proceedings). https://doi.org/10.1063/1.5087667

Author

Kodinzev, Ilia ; Lobinsky, Artem ; Tolstoy, Valeri. / Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium. State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018. editor / Yuri Petrov ; Oleg Vyvenko. American Institute of Physics, 2019. (AIP Conference Proceedings).

BibTeX

@inproceedings{c3155dc7923e4d99ac7c88a89846e578,
title = "Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium",
abstract = " Synthetic conditions of obtaining nickel phosphide nanolayers by Successive Ionic Layer Deposition (SILD) method are described. The samples were characterized via XRD, SEM, EDX and XPS. We demonstrate that NiP x amorphous nanolayers are formed on the surface and they include oxygen atoms forming Ni-OH and P-OH groups. Investigation of the electrocatalytic properties showed high activity of oxygen release during the electrolysis of water in the alkaline medium. Moreover, it was shown that the characteristics of such electrocatalysts changed in the series of samples synthesized after different number of SILD cycles. The best electrocatalytic properties belong to the sample which was acquired as a result of 10 cycles. It is characterized by overpotential values of 305, 390 and 418 mV, at currents of 20, 50 and 100 mA, respectively, as well as Tafel slope of 75 mV/dec. On the basis of the experimental results, it is suggested that the SILD method can be used to synthesize a wide range of nanocomposites that have improved electrocatalytic properties. ",
keywords = "Water splitting, oxygen evolution reaction, SILD, nickel phosphide, electrocatalyst, METAL, NANOCOMPOSITES",
author = "Ilia Kodinzev and Artem Lobinsky and Valeri Tolstoy",
year = "2019",
month = jan,
day = "15",
doi = "10.1063/1.5087667",
language = "English",
isbn = "9780735417922",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics",
editor = "Yuri Petrov and Oleg Vyvenko",
booktitle = "State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018",
address = "United States",
note = "International Conference on State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018 ; Conference date: 17-10-2018 Through 19-10-2018",

}

RIS

TY - GEN

T1 - Successive ionic layer deposition of NiP x nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium

AU - Kodinzev, Ilia

AU - Lobinsky, Artem

AU - Tolstoy, Valeri

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Synthetic conditions of obtaining nickel phosphide nanolayers by Successive Ionic Layer Deposition (SILD) method are described. The samples were characterized via XRD, SEM, EDX and XPS. We demonstrate that NiP x amorphous nanolayers are formed on the surface and they include oxygen atoms forming Ni-OH and P-OH groups. Investigation of the electrocatalytic properties showed high activity of oxygen release during the electrolysis of water in the alkaline medium. Moreover, it was shown that the characteristics of such electrocatalysts changed in the series of samples synthesized after different number of SILD cycles. The best electrocatalytic properties belong to the sample which was acquired as a result of 10 cycles. It is characterized by overpotential values of 305, 390 and 418 mV, at currents of 20, 50 and 100 mA, respectively, as well as Tafel slope of 75 mV/dec. On the basis of the experimental results, it is suggested that the SILD method can be used to synthesize a wide range of nanocomposites that have improved electrocatalytic properties.

AB - Synthetic conditions of obtaining nickel phosphide nanolayers by Successive Ionic Layer Deposition (SILD) method are described. The samples were characterized via XRD, SEM, EDX and XPS. We demonstrate that NiP x amorphous nanolayers are formed on the surface and they include oxygen atoms forming Ni-OH and P-OH groups. Investigation of the electrocatalytic properties showed high activity of oxygen release during the electrolysis of water in the alkaline medium. Moreover, it was shown that the characteristics of such electrocatalysts changed in the series of samples synthesized after different number of SILD cycles. The best electrocatalytic properties belong to the sample which was acquired as a result of 10 cycles. It is characterized by overpotential values of 305, 390 and 418 mV, at currents of 20, 50 and 100 mA, respectively, as well as Tafel slope of 75 mV/dec. On the basis of the experimental results, it is suggested that the SILD method can be used to synthesize a wide range of nanocomposites that have improved electrocatalytic properties.

KW - Water splitting

KW - oxygen evolution reaction

KW - SILD

KW - nickel phosphide

KW - electrocatalyst

KW - METAL

KW - NANOCOMPOSITES

UR - http://www.scopus.com/inward/record.url?scp=85060517457&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/successive-ionic-layer-deposition-nip-x-nanolayers-surface-nickel-foam-electrocatalytic-properties-o

U2 - 10.1063/1.5087667

DO - 10.1063/1.5087667

M3 - Conference contribution

AN - SCOPUS:85060517457

SN - 9780735417922

T3 - AIP Conference Proceedings

BT - State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018

A2 - Petrov, Yuri

A2 - Vyvenko, Oleg

PB - American Institute of Physics

T2 - International Conference on State-of-the-Art Trends of Scientific Research of Artificial and Natural Nanoobjects, STRANN 2018

Y2 - 17 October 2018 through 19 October 2018

ER -

ID: 42174203