Substituents effect on the electronic structure, spectra and photochemistry of [Ru(NH3)5(Py-X)]2+ complexes

Substituents effect on the electronic structure, spectra and photochemistry of [Ru(NH₃)₅(Py-X)]²⁺ complexes

Research output: Contribution to journal › Article › peer-review

Department of Physical Chemistry

DOI

https://doi.org/10.1016/j.ica.2003.06.008
Final published version

Olga V. Sizova
Nina V. Ivanova
Vladimir V. Sizov
Alexey Yu Ershov
Victor I. Baranovski

The diagrams of MLCT and d-d excited states of the complexes [Ru(NH ₃)₅(py-X)]²⁺ are calculated using semiempirical CINDO/S method. Comparison of the relative energies of MLCT and d-d excited states leads to the understanding of the background of the rules, found earlier by Ford et al., that govern photochemical activity of the Ru(II) complexes under consideration.

Original language	English
Pages (from-to)	354-360
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	357
Issue number	2
DOIs	https://doi.org/10.1016/j.ica.2003.06.008
State	Published - 30 Jan 2004

Research areas

dd-transitions, Metal to ligand charge transfer, Photochemistry, Ruthenium(II) complexes

Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

ID: 34660848