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Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt. / Sharutin, Vladimir V.; Sharutina, Olga K.; Novikov, Alexander S.; Adonin, Sergey A.

In: New Journal of Chemistry, Vol. 44, No. 34, 14.09.2020, p. 14339-14342.

Research output: Contribution to journal › Article › peer-review

Harvard

Sharutin, VV, Sharutina, OK, Novikov, AS & Adonin, SA 2020, 'Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt', New Journal of Chemistry, vol. 44, no. 34, pp. 14339-14342. https://doi.org/10.1039/d0nj02774j

APA

Sharutin, V. V., Sharutina, O. K., Novikov, A. S., & Adonin, S. A. (2020). Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt. New Journal of Chemistry, 44(34), 14339-14342. https://doi.org/10.1039/d0nj02774j

Vancouver

Sharutin VV, Sharutina OK, Novikov AS, Adonin SA. Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt. New Journal of Chemistry. 2020 Sep 14;44(34):14339-14342. https://doi.org/10.1039/d0nj02774j

Author

Sharutin, Vladimir V. ; Sharutina, Olga K. ; Novikov, Alexander S. ; Adonin, Sergey A. / Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt. In: New Journal of Chemistry. 2020 ; Vol. 44, No. 34. pp. 14339-14342.

BibTeX

@article{17fe1c941c66461ca6c385ce5b1c9ac4,
title = "Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt",
abstract = "The outcome of reactions of triarylantimony (Ar3Sb) with diiodine in benzene is strongly affected by the identity of the substituents. For R = 4-MePh, 3-MePh and 4-FPh, they form SbVderivatives Ar3SbI2, while for (2-MeO-5-BrC6H4)3Sb the reaction results in [(2-MeO-5-BrC6H4)3SbI](I3) where I is bound to the Sb center. The features of noncovalent interactions in the structure of the latter compound, as well as the electronic structure of the [(2-MeO-5-BrPh)3SbI]+cation, were studied by theoretical methods.",
author = "Sharutin, {Vladimir V.} and Sharutina, {Olga K.} and Novikov, {Alexander S.} and Adonin, {Sergey A.}",
year = "2020",
month = sep,
day = "14",
doi = "10.1039/d0nj02774j",
language = "English",
volume = "44",
pages = "14339--14342",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "34",

}

RIS

TY - JOUR

T1 - Substituent-dependent reactivity of triarylantimony(iii) toward I2 isolation of [Ar3SbI]+salt

AU - Sharutin, Vladimir V.

AU - Sharutina, Olga K.

AU - Novikov, Alexander S.

AU - Adonin, Sergey A.

PY - 2020/9/14

Y1 - 2020/9/14

N2 - The outcome of reactions of triarylantimony (Ar3Sb) with diiodine in benzene is strongly affected by the identity of the substituents. For R = 4-MePh, 3-MePh and 4-FPh, they form SbVderivatives Ar3SbI2, while for (2-MeO-5-BrC6H4)3Sb the reaction results in [(2-MeO-5-BrC6H4)3SbI](I3) where I is bound to the Sb center. The features of noncovalent interactions in the structure of the latter compound, as well as the electronic structure of the [(2-MeO-5-BrPh)3SbI]+cation, were studied by theoretical methods.

AB - The outcome of reactions of triarylantimony (Ar3Sb) with diiodine in benzene is strongly affected by the identity of the substituents. For R = 4-MePh, 3-MePh and 4-FPh, they form SbVderivatives Ar3SbI2, while for (2-MeO-5-BrC6H4)3Sb the reaction results in [(2-MeO-5-BrC6H4)3SbI](I3) where I is bound to the Sb center. The features of noncovalent interactions in the structure of the latter compound, as well as the electronic structure of the [(2-MeO-5-BrPh)3SbI]+cation, were studied by theoretical methods.

UR - http://www.scopus.com/inward/record.url?scp=85090991531&partnerID=8YFLogxK

U2 - 10.1039/d0nj02774j

DO - 10.1039/d0nj02774j

M3 - Article

AN - SCOPUS:85090991531

VL - 44

SP - 14339

EP - 14342

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 34

ER -

ID: 62499199