Research output: Contribution to journal › Article › peer-review
Subsolidus phase equilibria in the GdFeO3-SrFeO3-δ system in air. / Тugova, E.A.; Кrasilin, A.A.; Panchuk, V. V.; Semenov, V. G.; Gusarov, V. V.
In: Ceramics International, Vol. 46, No. 15, 15.10.2020, p. 24526-24533.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Subsolidus phase equilibria in the GdFeO3-SrFeO3-δ system in air
AU - Тugova, E.A.
AU - Кrasilin, A.A.
AU - Panchuk, V. V.
AU - Semenov, V. G.
AU - Gusarov, V. V.
N1 - Funding Information: The study was carried out within the framework of the State Assignment of Ioffe Institute. Publisher Copyright: © 2020 Elsevier Ltd and Techna Group S.r.l. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/10/15
Y1 - 2020/10/15
N2 - The paper considers phase equilibria in the subsolidus region of the GdFeO3-SrFeO3-δ system in air. By using X-ray powder diffraction, SEM/EDS, and Mössbauer spectroscopy, a GdFeO3-SrFeO3-δ phase diagram was constructed in the 1300–1500 °C temperature range. The samples of Gd1-xSrxFeO3-α for this study were synthesized by solid-phase chemical reactions. The study of phase equilibria in the GdFeO3-SrFeO3-δ system showed the presence of three areas, that is, of solid solutions based on the strontium-poor GdFeO3 orthorhombic phase, of the strontium-rich SrFeO3-δ cubic phase, as well as of an intermediate region in the mixture of these phases. The miscibility gap width (Δx) decreases from 0.54 to 0.35 with an increase in temperature from 1300 to 1500 °C.
AB - The paper considers phase equilibria in the subsolidus region of the GdFeO3-SrFeO3-δ system in air. By using X-ray powder diffraction, SEM/EDS, and Mössbauer spectroscopy, a GdFeO3-SrFeO3-δ phase diagram was constructed in the 1300–1500 °C temperature range. The samples of Gd1-xSrxFeO3-α for this study were synthesized by solid-phase chemical reactions. The study of phase equilibria in the GdFeO3-SrFeO3-δ system showed the presence of three areas, that is, of solid solutions based on the strontium-poor GdFeO3 orthorhombic phase, of the strontium-rich SrFeO3-δ cubic phase, as well as of an intermediate region in the mixture of these phases. The miscibility gap width (Δx) decreases from 0.54 to 0.35 with an increase in temperature from 1300 to 1500 °C.
KW - A. Powders: solid state reaction
KW - B. Electron microscopy
KW - B. X-ray methods
KW - D. Perovskites
KW - Solid solubility
KW - LN
KW - X-ray methods
KW - NONSTOICHIOMETRY
KW - CRYSTAL-STRUCTURE
KW - BEHAVIOR
KW - Perovskites
KW - SEGREGATION
KW - Electron microscopy
KW - OXYGEN
KW - PEROVSKITE
KW - COMPLEX OXIDES
KW - Powders: solid state reaction
KW - MOSSBAUER
KW - DIAGRAM
UR - http://www.scopus.com/inward/record.url?scp=85087676242&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2020.06.239
DO - 10.1016/j.ceramint.2020.06.239
M3 - Article
AN - SCOPUS:85087676242
VL - 46
SP - 24526
EP - 24533
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 15
ER -
ID: 70046287