Study of Tetraethylammonium and Lithium Chlorides Dissociation in Acetonitrile Solutions

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Study of Tetraethylammonium and Lithium Chlorides Dissociation in Acetonitrile Solutions. / Vidiakina, A. A.; Bogachev, N. A.; Skripkin, M. Yu ; Mereshchenko, A. S.

In: Russian Journal of General Chemistry, Vol. 90, No. 9, 01.09.2020, p. 1703-1705.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3a7652fd89ed43969af89bdf50389532,

title = "Study of Tetraethylammonium and Lithium Chlorides Dissociation in Acetonitrile Solutions",

abstract = "Abstract: Solutions of tetraethylammonium and lithium chlorides in acetonitrile were studied by electronic absorption spectroscopy. It was shown that at concentrations up to 100 mmol/L tetraethylammonium chloride completely dissociates. The association constant of lithium chloride in acetonitrile (Kass = 4800 mol–1 L) was determined by the spectrophotometric method. The electronic absorption spectra of the Li+Cl– ionic pair and Cl– anion in acetonitrile were studied.",

keywords = "association constant, lithium chloride, tetraethylammonium chloride, TETRAALKYLAMMONIUM SALTS",

author = "Vidiakina, {A. A.} and Bogachev, {N. A.} and Skripkin, {M. Yu} and Mereshchenko, {A. S.}",

year = "2020",

month = sep,

day = "1",

doi = "10.1134/S1070363220090170",

language = "English",

volume = "90",

pages = "1703--1705",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "9",

}

RIS

TY - JOUR

T1 - Study of Tetraethylammonium and Lithium Chlorides Dissociation in Acetonitrile Solutions

AU - Vidiakina, A. A.

AU - Bogachev, N. A.

AU - Skripkin, M. Yu

AU - Mereshchenko, A. S.

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Abstract: Solutions of tetraethylammonium and lithium chlorides in acetonitrile were studied by electronic absorption spectroscopy. It was shown that at concentrations up to 100 mmol/L tetraethylammonium chloride completely dissociates. The association constant of lithium chloride in acetonitrile (Kass = 4800 mol–1 L) was determined by the spectrophotometric method. The electronic absorption spectra of the Li+Cl– ionic pair and Cl– anion in acetonitrile were studied.

AB - Abstract: Solutions of tetraethylammonium and lithium chlorides in acetonitrile were studied by electronic absorption spectroscopy. It was shown that at concentrations up to 100 mmol/L tetraethylammonium chloride completely dissociates. The association constant of lithium chloride in acetonitrile (Kass = 4800 mol–1 L) was determined by the spectrophotometric method. The electronic absorption spectra of the Li+Cl– ionic pair and Cl– anion in acetonitrile were studied.

KW - association constant

KW - lithium chloride

KW - tetraethylammonium chloride

KW - TETRAALKYLAMMONIUM SALTS

UR - http://www.scopus.com/inward/record.url?scp=85092302915&partnerID=8YFLogxK

U2 - 10.1134/S1070363220090170

DO - 10.1134/S1070363220090170

M3 - Article

AN - SCOPUS:85092302915

VL - 90

SP - 1703

EP - 1705

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 9

ER -

ID: 70632567