Standard

Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane. / Katlenok, E. A.; Zolotarev, A. A.; Smirnov, A. Yu; Ivanov, S. N.; Baichurin, R. I.; Makarenko, S. V.; Balashev, K. P.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 5, 04.05.2017, p. 297-303.

Research output: Contribution to journal › Article › peer-review

Harvard

Katlenok, EA, Zolotarev, AA, Smirnov, AY, Ivanov, SN, Baichurin, RI, Makarenko, SV & Balashev, KP 2017, 'Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 5, pp. 297-303. https://doi.org/10.1134/S1070328417040029

APA

Katlenok, E. A., Zolotarev, A. A., Smirnov, A. Y., Ivanov, S. N., Baichurin, R. I., Makarenko, S. V., & Balashev, K. P. (2017). Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(5), 297-303. https://doi.org/10.1134/S1070328417040029

Vancouver

Katlenok EA, Zolotarev AA, Smirnov AY, Ivanov SN, Baichurin RI, Makarenko SV et al. Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 May 4;43(5):297-303. https://doi.org/10.1134/S1070328417040029

Author

Katlenok, E. A. ; Zolotarev, A. A. ; Smirnov, A. Yu ; Ivanov, S. N. ; Baichurin, R. I. ; Makarenko, S. V. ; Balashev, K. P. / Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Vol. 43, No. 5. pp. 297-303.

BibTeX

@article{3ae94912326e4a3db234e19982f5f2f5,
title = "Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane",
abstract = "The distorted square pyramidal structures of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and flexible 1,4,7-trithiocyclononane are shown by X-ray diffraction analysis, IR spectroscopy, and 1Н, 13С{1H{, and 195Pt NMR spectroscopy. The axial interaction of the dZ2 orbital of Pt(II) and Pd(II) with the S atom of 1,4,7-trithiocyclononane results in the temperature quenching of the intraligand phosphorescence of the cyclometallated complexes in a solution and the one-electron ligand- and metal-centered reduction and oxidation of the complexes with the formation of the relatively stable Pd(III) complex (CIF file CCDC no. 1483011).",
keywords = "С NMR, Pt NMR, 1Н NMR, IR spectroscopy, optical absorption and emission spectroscopy, Pd(II) and Pt(II) complexes with metallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane, reduction and oxidation voltammograms of complexes, X-ray diffraction analysis",
author = "Katlenok, {E. A.} and Zolotarev, {A. A.} and Smirnov, {A. Yu} and Ivanov, {S. N.} and Baichurin, {R. I.} and Makarenko, {S. V.} and Balashev, {K. P.}",
year = "2017",
month = may,
day = "4",
doi = "10.1134/S1070328417040029",
language = "English",
volume = "43",
pages = "297--303",
journal = "Russian Journal of Coordination Chemistry",
issn = "1070-3284",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Structures and optical and electrochemical properties of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane

AU - Katlenok, E. A.

AU - Zolotarev, A. A.

AU - Smirnov, A. Yu

AU - Ivanov, S. N.

AU - Baichurin, R. I.

AU - Makarenko, S. V.

AU - Balashev, K. P.

PY - 2017/5/4

Y1 - 2017/5/4

N2 - The distorted square pyramidal structures of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and flexible 1,4,7-trithiocyclononane are shown by X-ray diffraction analysis, IR spectroscopy, and 1Н, 13С{1H{, and 195Pt NMR spectroscopy. The axial interaction of the dZ2 orbital of Pt(II) and Pd(II) with the S atom of 1,4,7-trithiocyclononane results in the temperature quenching of the intraligand phosphorescence of the cyclometallated complexes in a solution and the one-electron ligand- and metal-centered reduction and oxidation of the complexes with the formation of the relatively stable Pd(III) complex (CIF file CCDC no. 1483011).

AB - The distorted square pyramidal structures of the Pt(II) and Pd(II) complexes with cyclometallated 2-phenylbenzothiazole and flexible 1,4,7-trithiocyclononane are shown by X-ray diffraction analysis, IR spectroscopy, and 1Н, 13С{1H{, and 195Pt NMR spectroscopy. The axial interaction of the dZ2 orbital of Pt(II) and Pd(II) with the S atom of 1,4,7-trithiocyclononane results in the temperature quenching of the intraligand phosphorescence of the cyclometallated complexes in a solution and the one-electron ligand- and metal-centered reduction and oxidation of the complexes with the formation of the relatively stable Pd(III) complex (CIF file CCDC no. 1483011).

KW - С NMR

KW - Pt NMR

KW - 1Н NMR

KW - IR spectroscopy

KW - optical absorption and emission spectroscopy

KW - Pd(II) and Pt(II) complexes with metallated 2-phenylbenzothiazole and 1,4,7-trithiocyclononane

KW - reduction and oxidation voltammograms of complexes

KW - X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85018790896&partnerID=8YFLogxK

U2 - 10.1134/S1070328417040029

DO - 10.1134/S1070328417040029

M3 - Article

AN - SCOPUS:85018790896

VL - 43

SP - 297

EP - 303

JO - Russian Journal of Coordination Chemistry

JF - Russian Journal of Coordination Chemistry

SN - 1070-3284

IS - 5

ER -

ID: 9131399