Structure of lead (II) tetrafluorostannate (II) prepared by hydrothermal synthesis

Research output: Contribution to journal › Article › peer-review

Department of Solid State Chemistry

DOI

https://doi.org/10.1016/0167-2738(91)90182-B
Final published version

S. V. Chernov
A. L. Moskvin
I. V. Murin

The structure of lead (II) tetrafluorostannate (II) (PbSnF₄) prepared by hydrothermal synthesis was determined. The parameters of the orthorhombic unit cell are a = 22.845 (2) A ̊, b = 5.850 (2) A ̊, c = 6.021 (2) A ̊, V = 804.6(6) Å³, ρ_calc. = 6.63g cm³, z = 8, space group Aba2. The high F^- mobility in this compound was found to be correlated to the possibility for tin atoms to have two alternative fluoride ions coordinations, and/or to the great number of partially occupied F sites.

Original language	English
Pages (from-to)	71-73
Number of pages	3
Journal	Solid State Ionics
Volume	47
Issue number	1-2
DOIs	https://doi.org/10.1016/0167-2738(91)90182-B
State	Published - Aug 1991

Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

ID: 88001247