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Structure of fluorescent metal clusters on a DNA template. / Vdovichev, A A; Sych, T S; Reveguk, Z V; Smirnova, A A; Maksimov, D A; Ramazanov, R R; Kononov, A I.

In: Journal of Physics: Conference Series, Vol. 741, No. 1, 2016, p. 012069.

Research output: Contribution to journal › Article › peer-review

Harvard

Vdovichev, AA, Sych, TS, Reveguk, ZV, Smirnova, AA, Maksimov, DA, Ramazanov, RR & Kononov, AI 2016, 'Structure of fluorescent metal clusters on a DNA template', Journal of Physics: Conference Series, vol. 741, no. 1, pp. 012069. https://doi.org/10.1088/1742-6596/741/1/012069

APA

Vdovichev, A. A., Sych, T. S., Reveguk, Z. V., Smirnova, A. A., Maksimov, D. A., Ramazanov, R. R., & Kononov, A. I. (2016). Structure of fluorescent metal clusters on a DNA template. Journal of Physics: Conference Series, 741(1), 012069. https://doi.org/10.1088/1742-6596/741/1/012069

Vancouver

Vdovichev AA, Sych TS, Reveguk ZV, Smirnova AA, Maksimov DA, Ramazanov RR et al. Structure of fluorescent metal clusters on a DNA template. Journal of Physics: Conference Series. 2016;741(1):012069. https://doi.org/10.1088/1742-6596/741/1/012069

Author

Vdovichev, A A ; Sych, T S ; Reveguk, Z V ; Smirnova, A A ; Maksimov, D A ; Ramazanov, R R ; Kononov, A I. / Structure of fluorescent metal clusters on a DNA template. In: Journal of Physics: Conference Series. 2016 ; Vol. 741, No. 1. pp. 012069.

BibTeX

@article{86089def33354adea9bb6571e8fd490a,
title = "Structure of fluorescent metal clusters on a DNA template",
abstract = "Luminescent metal clusters are a subject of growing interest in recent years due to their bright emission from visible to near infrared range. Detailed structure of the fluorescent complexes of Ag and other metal clusters with ligands still remains a challenging task. In this joint experimental and theoretical study we synthesized Ag-DNA complexes on a DNA oligonucleotide emitting in violet- green spectral range. The structure of DNA template was determined by means of various spectral measurements (CD, MS, XPS). Comparison of the experimental fluorescent excitation spectra and calculated absorption spectra for different QM/MM optimized structures allowed us to determine the detailed structure of the green cluster containing three silver atoms in the stem of the DNA hairpin structure stabilized by cytosine-Ag+-cytosine bonds.",
author = "Vdovichev, {A A} and Sych, {T S} and Reveguk, {Z V} and Smirnova, {A A} and Maksimov, {D A} and Ramazanov, {R R} and Kononov, {A I}",
year = "2016",
doi = "10.1088/1742-6596/741/1/012069",
language = "English",
volume = "741",
pages = "012069",
journal = "Journal of Physics: Conference Series",
issn = "1742-6588",
publisher = "IOP Publishing Ltd.",
number = "1",

}

RIS

TY - JOUR

T1 - Structure of fluorescent metal clusters on a DNA template

AU - Vdovichev, A A

AU - Sych, T S

AU - Reveguk, Z V

AU - Smirnova, A A

AU - Maksimov, D A

AU - Ramazanov, R R

AU - Kononov, A I

PY - 2016

Y1 - 2016

N2 - Luminescent metal clusters are a subject of growing interest in recent years due to their bright emission from visible to near infrared range. Detailed structure of the fluorescent complexes of Ag and other metal clusters with ligands still remains a challenging task. In this joint experimental and theoretical study we synthesized Ag-DNA complexes on a DNA oligonucleotide emitting in violet- green spectral range. The structure of DNA template was determined by means of various spectral measurements (CD, MS, XPS). Comparison of the experimental fluorescent excitation spectra and calculated absorption spectra for different QM/MM optimized structures allowed us to determine the detailed structure of the green cluster containing three silver atoms in the stem of the DNA hairpin structure stabilized by cytosine-Ag+-cytosine bonds.

AB - Luminescent metal clusters are a subject of growing interest in recent years due to their bright emission from visible to near infrared range. Detailed structure of the fluorescent complexes of Ag and other metal clusters with ligands still remains a challenging task. In this joint experimental and theoretical study we synthesized Ag-DNA complexes on a DNA oligonucleotide emitting in violet- green spectral range. The structure of DNA template was determined by means of various spectral measurements (CD, MS, XPS). Comparison of the experimental fluorescent excitation spectra and calculated absorption spectra for different QM/MM optimized structures allowed us to determine the detailed structure of the green cluster containing three silver atoms in the stem of the DNA hairpin structure stabilized by cytosine-Ag+-cytosine bonds.

U2 - 10.1088/1742-6596/741/1/012069

DO - 10.1088/1742-6596/741/1/012069

M3 - Article

VL - 741

SP - 012069

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

SN - 1742-6588

IS - 1

ER -

ID: 7589666