Research output: Contribution to journal › Article › peer-review
Structure of cesium–borosilicate glasses according to NMR spectroscopy. / Osipov, A. A.; Eremyashev, V. E.; Mazur, A. S.; Tolstoi, P. M.; Osipova, L. M.
In: Glass Physics and Chemistry, Vol. 43, No. 4, 01.07.2017, p. 287-293.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Structure of cesium–borosilicate glasses according to NMR spectroscopy
AU - Osipov, A. A.
AU - Eremyashev, V. E.
AU - Mazur, A. S.
AU - Tolstoi, P. M.
AU - Osipova, L. M.
N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by state contract no. АААА-А16-116012510127-9 and a state contract of the Ministry of Education and Science (project no. 11.9643.2017/BCh). Publisher Copyright: © 2017, Pleiades Publishing, Ltd. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2017/7/1
Y1 - 2017/7/1
N2 - The local structure of cesium-borosilicate glasses with various Cs2O and B2O3 proportions and constant SiO2 content (50 mol %) is studied with 11B, 29Si, and 133Cs MAS NMR spectroscopy. The portions of three- and four-fold Si atoms are determined, as well as the concentrations of various silicate Qn units. Our experimental data are compared with the predictions of Dell’s model and thermodynamic modeling for sodium–borosilicate analogs of the glasses studied.
AB - The local structure of cesium-borosilicate glasses with various Cs2O and B2O3 proportions and constant SiO2 content (50 mol %) is studied with 11B, 29Si, and 133Cs MAS NMR spectroscopy. The portions of three- and four-fold Si atoms are determined, as well as the concentrations of various silicate Qn units. Our experimental data are compared with the predictions of Dell’s model and thermodynamic modeling for sodium–borosilicate analogs of the glasses studied.
KW - borosilicate glasses
KW - NMR spectroscopy
KW - structure
UR - http://www.scopus.com/inward/record.url?scp=85028042741&partnerID=8YFLogxK
U2 - 10.1134/S1087659617040113
DO - 10.1134/S1087659617040113
M3 - Article
AN - SCOPUS:85028042741
VL - 43
SP - 287
EP - 293
JO - Glass Physics and Chemistry
JF - Glass Physics and Chemistry
SN - 1087-6596
IS - 4
ER -
ID: 9328038