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Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data. / Davidian, A.G.; Kudrev, A.G.; Myund, L.A.; Khlynova, O.S.; Khripun, M.K.

In: Russian Journal of General Chemistry, Vol. 84, No. 10, 2014, p. 1877-1887.

Research output: Contribution to journal › Article › peer-review

Harvard

Davidian, AG, Kudrev, AG, Myund, LA, Khlynova, OS & Khripun, MK 2014, 'Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data', Russian Journal of General Chemistry, vol. 84, no. 10, pp. 1877-1887. https://doi.org/10.1134/S1070363214100028

APA

Davidian, A. G., Kudrev, A. G., Myund, L. A., Khlynova, O. S., & Khripun, M. K. (2014). Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data. Russian Journal of General Chemistry, 84(10), 1877-1887. https://doi.org/10.1134/S1070363214100028

Vancouver

Davidian AG, Kudrev AG, Myund LA, Khlynova OS, Khripun MK. Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data. Russian Journal of General Chemistry. 2014;84(10):1877-1887. https://doi.org/10.1134/S1070363214100028

Author

Davidian, A.G. ; Kudrev, A.G. ; Myund, L.A. ; Khlynova, O.S. ; Khripun, M.K. / Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data. In: Russian Journal of General Chemistry. 2014 ; Vol. 84, No. 10. pp. 1877-1887.

BibTeX

@article{70d4a6059ac34250a044624726f78ca0,
title = "Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data",
abstract = "{\textcopyright} Pleiades Publishing, Ltd., 2014. {\textcopyright} A.G. Davidian, A.G. Kudrev, L.A. Myund, O.S. Khlynova, M.K. Khripun, 2014. The IR spectra of aqueous solutions of MClO4, MNO3, MCl (M = Li, Na), CsCl, and Na2SO4 were measured at frequencies of 5400-7500 cm-1 over a wide concentration range from 0.12 M up to saturation concentrations at 25°C. Chemometric analysis of the experimental data matrix was performed. Regularity was detected in distribution of the IR spectra of the studied aqueous solutions on the the plot of analysis scores by the principal component method depending on the nature of the anion-water interaction. The influence of the nature of the salt anion and cation on the water structure in aqueous electrolyte solutions was demonstrated. The existence and interconversion of the spectral forms of water with changing electrolyte concentration in solution were revealed.",
author = "A.G. Davidian and A.G. Kudrev and L.A. Myund and O.S. Khlynova and M.K. Khripun",
year = "2014",
doi = "10.1134/S1070363214100028",
language = "English",
volume = "84",
pages = "1877--1887",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Structure of aqueous electrolyte solutions estimated by near infrared spectroscopy and chemometric analysis of spectral data

AU - Davidian, A.G.

AU - Kudrev, A.G.

AU - Myund, L.A.

AU - Khlynova, O.S.

AU - Khripun, M.K.

PY - 2014

Y1 - 2014

N2 - © Pleiades Publishing, Ltd., 2014. © A.G. Davidian, A.G. Kudrev, L.A. Myund, O.S. Khlynova, M.K. Khripun, 2014. The IR spectra of aqueous solutions of MClO4, MNO3, MCl (M = Li, Na), CsCl, and Na2SO4 were measured at frequencies of 5400-7500 cm-1 over a wide concentration range from 0.12 M up to saturation concentrations at 25°C. Chemometric analysis of the experimental data matrix was performed. Regularity was detected in distribution of the IR spectra of the studied aqueous solutions on the the plot of analysis scores by the principal component method depending on the nature of the anion-water interaction. The influence of the nature of the salt anion and cation on the water structure in aqueous electrolyte solutions was demonstrated. The existence and interconversion of the spectral forms of water with changing electrolyte concentration in solution were revealed.

AB - © Pleiades Publishing, Ltd., 2014. © A.G. Davidian, A.G. Kudrev, L.A. Myund, O.S. Khlynova, M.K. Khripun, 2014. The IR spectra of aqueous solutions of MClO4, MNO3, MCl (M = Li, Na), CsCl, and Na2SO4 were measured at frequencies of 5400-7500 cm-1 over a wide concentration range from 0.12 M up to saturation concentrations at 25°C. Chemometric analysis of the experimental data matrix was performed. Regularity was detected in distribution of the IR spectra of the studied aqueous solutions on the the plot of analysis scores by the principal component method depending on the nature of the anion-water interaction. The influence of the nature of the salt anion and cation on the water structure in aqueous electrolyte solutions was demonstrated. The existence and interconversion of the spectral forms of water with changing electrolyte concentration in solution were revealed.

U2 - 10.1134/S1070363214100028

DO - 10.1134/S1070363214100028

M3 - Article

VL - 84

SP - 1877

EP - 1887

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 5729654