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Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements : XVIII. Magnetic susceptibility and ESR spectra of Bi2BaNb2–2xMn2xO9–δ solid solutions with layered perovskite-like structure. / Chezhina, N. V.; Korolev, D. A.; Fedorova, A. V.; Zhuk, N. A.; Feltsinger, L. S.; Pryanishnikova, E. A.; Lutoev, V. P.; Makeev, B. A.

In: Russian Journal of General Chemistry, Vol. 87, No. 11, 01.11.2017, p. 2525-2532.

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@article{3c9c05e8137c41259da9383dc5c1a958,
title = "Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVIII. Magnetic susceptibility and ESR spectra of Bi2BaNb2–2xMn2xO9–δ solid solutions with layered perovskite-like structure",
abstract = "On the basis of the data of ESR and magnetic susceptibility of Bi2BaNb2–2xMn2xO9–δ solid solutions with perovskite-like structure ferro- and aniferromagnetic bonded dimers, trimers, and tetramers of Mn(II), Mn(III), and Mn(IV) atoms in various valence states were found. The distribution of aggregates and exchange parameters in the clusters were calculated as a function of fraction x of manganese atoms in the solid solutions. In the ESR spectra of diluted solid solutions there are absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms.",
keywords = "ESR spectroscopy, perovskite-like oxides containing bismuth",
author = "Chezhina, {N. V.} and Korolev, {D. A.} and Fedorova, {A. V.} and Zhuk, {N. A.} and Feltsinger, {L. S.} and Pryanishnikova, {E. A.} and Lutoev, {V. P.} and Makeev, {B. A.}",
year = "2017",
month = nov,
day = "1",
doi = "10.1134/S1070363217110032",
language = "English",
volume = "87",
pages = "2525--2532",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "11",

}

RIS

TY - JOUR

T1 - Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements

T2 - XVIII. Magnetic susceptibility and ESR spectra of Bi2BaNb2–2xMn2xO9–δ solid solutions with layered perovskite-like structure

AU - Chezhina, N. V.

AU - Korolev, D. A.

AU - Fedorova, A. V.

AU - Zhuk, N. A.

AU - Feltsinger, L. S.

AU - Pryanishnikova, E. A.

AU - Lutoev, V. P.

AU - Makeev, B. A.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - On the basis of the data of ESR and magnetic susceptibility of Bi2BaNb2–2xMn2xO9–δ solid solutions with perovskite-like structure ferro- and aniferromagnetic bonded dimers, trimers, and tetramers of Mn(II), Mn(III), and Mn(IV) atoms in various valence states were found. The distribution of aggregates and exchange parameters in the clusters were calculated as a function of fraction x of manganese atoms in the solid solutions. In the ESR spectra of diluted solid solutions there are absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms.

AB - On the basis of the data of ESR and magnetic susceptibility of Bi2BaNb2–2xMn2xO9–δ solid solutions with perovskite-like structure ferro- and aniferromagnetic bonded dimers, trimers, and tetramers of Mn(II), Mn(III), and Mn(IV) atoms in various valence states were found. The distribution of aggregates and exchange parameters in the clusters were calculated as a function of fraction x of manganese atoms in the solid solutions. In the ESR spectra of diluted solid solutions there are absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms.

KW - ESR spectroscopy

KW - perovskite-like oxides containing bismuth

UR - http://www.scopus.com/inward/record.url?scp=85038411033&partnerID=8YFLogxK

U2 - 10.1134/S1070363217110032

DO - 10.1134/S1070363217110032

M3 - Article

AN - SCOPUS:85038411033

VL - 87

SP - 2525

EP - 2532

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 11

ER -

ID: 33891822