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Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction. / Smirnov, V. M.; Voronkov, G. P.; Semenov, V. G.; Povarov, V. G.; Gittsovich, V. N.; Sinel'nikov, B. M.; Murin, I. V.

In: Russian Journal of General Chemistry, Vol. 71, No. 10, 10.2001, p. 1506-1512.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnov, VM, Voronkov, GP, Semenov, VG, Povarov, VG, Gittsovich, VN, Sinel'nikov, BM & Murin, IV 2001, 'Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction', Russian Journal of General Chemistry, vol. 71, no. 10, pp. 1506-1512. https://doi.org/10.1023/A:1013965912185

APA

Smirnov, V. M., Voronkov, G. P., Semenov, V. G., Povarov, V. G., Gittsovich, V. N., Sinel'nikov, B. M., & Murin, I. V. (2001). Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction. Russian Journal of General Chemistry, 71(10), 1506-1512. https://doi.org/10.1023/A:1013965912185

Vancouver

Smirnov VM, Voronkov GP, Semenov VG, Povarov VG, Gittsovich VN, Sinel'nikov BM et al. Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction. Russian Journal of General Chemistry. 2001 Oct;71(10):1506-1512. https://doi.org/10.1023/A:1013965912185

Author

Smirnov, V. M. ; Voronkov, G. P. ; Semenov, V. G. ; Povarov, V. G. ; Gittsovich, V. N. ; Sinel'nikov, B. M. ; Murin, I. V. / Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction. In: Russian Journal of General Chemistry. 2001 ; Vol. 71, No. 10. pp. 1506-1512.

BibTeX

@article{7d753398970047a8a8bcc6c941130619,
title = "Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction",
abstract = "Transport reduction was shown to allow finely controlling the Fe+3/Fe+2 ratio in iron-oxygen two-dimensional nanostructures (nanolayers, thickness 3-15 {\AA}) on silica. It was found by M{\"o}ssbauer spectroscopy that isolated surface iron-oxygen groups →-Si-O-Fe(OH)2 and (→Si-O-)2FeOH are not reduced at 400-600°C, which is explained by their covalent bonding with silica. The transport reduction of samples with applied nanolayers (one and four) at T ≥ 600°C was shown to form bulk phases [iron(II) silicate and metallic iron] on the silica surface. The features of structural-chemical transformations on transport reduction of iron-oxygen nanolayers on supports are primarily associated with the specifics of phase formation in nanostructures.",
author = "Smirnov, {V. M.} and Voronkov, {G. P.} and Semenov, {V. G.} and Povarov, {V. G.} and Gittsovich, {V. N.} and Sinel'nikov, {B. M.} and Murin, {I. V.}",
note = "Funding Information: The work was financially supported by the Russian Foundation for Basic Research (project no. 99-03-32 010) and the Integratsiya Program (project no. A-0 146).",
year = "2001",
month = oct,
doi = "10.1023/A:1013965912185",
language = "English",
volume = "71",
pages = "1506--1512",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Structural-chemical transformations of two-dimensional iron-oxygen nanostructures in the course of transport reduction

AU - Smirnov, V. M.

AU - Voronkov, G. P.

AU - Semenov, V. G.

AU - Povarov, V. G.

AU - Gittsovich, V. N.

AU - Sinel'nikov, B. M.

AU - Murin, I. V.

N1 - Funding Information: The work was financially supported by the Russian Foundation for Basic Research (project no. 99-03-32 010) and the Integratsiya Program (project no. A-0 146).

PY - 2001/10

Y1 - 2001/10

N2 - Transport reduction was shown to allow finely controlling the Fe+3/Fe+2 ratio in iron-oxygen two-dimensional nanostructures (nanolayers, thickness 3-15 Å) on silica. It was found by Mössbauer spectroscopy that isolated surface iron-oxygen groups →-Si-O-Fe(OH)2 and (→Si-O-)2FeOH are not reduced at 400-600°C, which is explained by their covalent bonding with silica. The transport reduction of samples with applied nanolayers (one and four) at T ≥ 600°C was shown to form bulk phases [iron(II) silicate and metallic iron] on the silica surface. The features of structural-chemical transformations on transport reduction of iron-oxygen nanolayers on supports are primarily associated with the specifics of phase formation in nanostructures.

AB - Transport reduction was shown to allow finely controlling the Fe+3/Fe+2 ratio in iron-oxygen two-dimensional nanostructures (nanolayers, thickness 3-15 Å) on silica. It was found by Mössbauer spectroscopy that isolated surface iron-oxygen groups →-Si-O-Fe(OH)2 and (→Si-O-)2FeOH are not reduced at 400-600°C, which is explained by their covalent bonding with silica. The transport reduction of samples with applied nanolayers (one and four) at T ≥ 600°C was shown to form bulk phases [iron(II) silicate and metallic iron] on the silica surface. The features of structural-chemical transformations on transport reduction of iron-oxygen nanolayers on supports are primarily associated with the specifics of phase formation in nanostructures.

UR - http://www.scopus.com/inward/record.url?scp=0035470932&partnerID=8YFLogxK

U2 - 10.1023/A:1013965912185

DO - 10.1023/A:1013965912185

M3 - Article

AN - SCOPUS:0035470932

VL - 71

SP - 1506

EP - 1512

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 88010148