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Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr). / Zubkov, V. G.; Surat, L. L.; Tyutyunnik, A. P.; Berger, I. F.; Tarakina, N. V.; Slobodin, B. V.; Kuznetsov, M. V.; Denisova, T. A.; Zhuravlev, N. A.; Perelyaeva, L. A.; Baklanova, I. V.; Shein, I. R.; Ivanovskii, A. L.; Shulgin, B. V.; Ishchenko, A. V.; Tcherepanov, A. N.; Svensson, G.; Forslund, B.; Skripkin, M. Yu.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 77, No. 17, 174113, 20.05.2008.

Research output: Contribution to journal › Article › peer-review

Harvard

Zubkov, VG, Surat, LL, Tyutyunnik, AP, Berger, IF, Tarakina, NV, Slobodin, BV, Kuznetsov, MV, Denisova, TA, Zhuravlev, NA, Perelyaeva, LA, Baklanova, IV, Shein, IR, Ivanovskii, AL, Shulgin, BV, Ishchenko, AV, Tcherepanov, AN, Svensson, G, Forslund, B & Skripkin, MY 2008, 'Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr)', Physical Review B - Condensed Matter and Materials Physics, vol. 77, no. 17, 174113. https://doi.org/10.1103/PhysRevB.77.174113

APA

Zubkov, V. G., Surat, L. L., Tyutyunnik, A. P., Berger, I. F., Tarakina, N. V., Slobodin, B. V., Kuznetsov, M. V., Denisova, T. A., Zhuravlev, N. A., Perelyaeva, L. A., Baklanova, I. V., Shein, I. R., Ivanovskii, A. L., Shulgin, B. V., Ishchenko, A. V., Tcherepanov, A. N., Svensson, G., Forslund, B., & Skripkin, M. Y. (2008). Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr). Physical Review B - Condensed Matter and Materials Physics, 77(17), [174113]. https://doi.org/10.1103/PhysRevB.77.174113

Vancouver

Zubkov VG, Surat LL, Tyutyunnik AP, Berger IF, Tarakina NV, Slobodin BV et al. Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr). Physical Review B - Condensed Matter and Materials Physics. 2008 May 20;77(17). 174113. https://doi.org/10.1103/PhysRevB.77.174113

Author

Zubkov, V. G. ; Surat, L. L. ; Tyutyunnik, A. P. ; Berger, I. F. ; Tarakina, N. V. ; Slobodin, B. V. ; Kuznetsov, M. V. ; Denisova, T. A. ; Zhuravlev, N. A. ; Perelyaeva, L. A. ; Baklanova, I. V. ; Shein, I. R. ; Ivanovskii, A. L. ; Shulgin, B. V. ; Ishchenko, A. V. ; Tcherepanov, A. N. ; Svensson, G. ; Forslund, B. ; Skripkin, M. Yu. / Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr). In: Physical Review B - Condensed Matter and Materials Physics. 2008 ; Vol. 77, No. 17.

BibTeX

@article{bf75f0eaaf9e49d88e2ebbb347ee0ab8,
title = "Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr)",
abstract = "The physical properties of the family of cyclotetravanadates A2 M (VO3) 4, where A=Na,Ag and M=Ca,Sr, have been studied by means of x-ray powder diffraction, neutron diffraction, electron diffraction, infrared, Raman, NMR, photoexcitation and pulse cathode beam excitation, and x-ray photoelectron spectroscopies, and band structure calculations. The differences between the structural, vibrational, luminescence, and electronic properties of the alkali metal-containing [Na2 Ca (VO3) 4 and Na2 Sr (VO3) 4] and the d metal-containing cyclotetravanadates [Ag2 Ca (VO3) 4 and Ag2 Sr (VO3) 4] are analyzed. Na2 Ca (VO3) 4, Ag2 Ca (VO3) 4, Na2 Sr (VO3) 4, and Ag2 Sr (VO3) 4 have tetragonal structures, P4/nbm, with a=10.43849 (6), 10.44524 (5), 10.63449 (4), and 10.62574 (6), and c=4.93873 (5), 4.96845 (5), 4.96205 (4), and 4.97930 (4) {\AA}, respectively. The main structural feature of A2 M (VO3) 4 is the tetracyclic [V4 O12] units. The hybridized O2p-V3d states of the tetracyclic [V4 O12] units have a dominant influence on the electronic structure of these compounds. The compounds are semiconducting with a local density approximation band gap increasing from 1.85 eV for Ag2 Ca (VO3) 4 to 3.02 eV for Na2 Ca (VO3) 4. The prospects of these compounds as advanced materials for detectors of photon and corpuscular radiation as well as for color correction of light emission sources such as lamp and light emitting diode sources are discussed.",
author = "Zubkov, {V. G.} and Surat, {L. L.} and Tyutyunnik, {A. P.} and Berger, {I. F.} and Tarakina, {N. V.} and Slobodin, {B. V.} and Kuznetsov, {M. V.} and Denisova, {T. A.} and Zhuravlev, {N. A.} and Perelyaeva, {L. A.} and Baklanova, {I. V.} and Shein, {I. R.} and Ivanovskii, {A. L.} and Shulgin, {B. V.} and Ishchenko, {A. V.} and Tcherepanov, {A. N.} and G. Svensson and B. Forslund and Skripkin, {M. Yu}",
year = "2008",
month = may,
day = "20",
doi = "10.1103/PhysRevB.77.174113",
language = "English",
volume = "77",
journal = "Physical Review B-Condensed Matter",
issn = "1098-0121",
publisher = "American Physical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Structural, vibrational, electronic, and luminescence properties of the cyclotetravanadates A2 M (VO3) 4 (A=Na,Ag; M=Ca,Sr)

AU - Zubkov, V. G.

AU - Surat, L. L.

AU - Tyutyunnik, A. P.

AU - Berger, I. F.

AU - Tarakina, N. V.

AU - Slobodin, B. V.

AU - Kuznetsov, M. V.

AU - Denisova, T. A.

AU - Zhuravlev, N. A.

AU - Perelyaeva, L. A.

AU - Baklanova, I. V.

AU - Shein, I. R.

AU - Ivanovskii, A. L.

AU - Shulgin, B. V.

AU - Ishchenko, A. V.

AU - Tcherepanov, A. N.

AU - Svensson, G.

AU - Forslund, B.

AU - Skripkin, M. Yu

PY - 2008/5/20

Y1 - 2008/5/20

N2 - The physical properties of the family of cyclotetravanadates A2 M (VO3) 4, where A=Na,Ag and M=Ca,Sr, have been studied by means of x-ray powder diffraction, neutron diffraction, electron diffraction, infrared, Raman, NMR, photoexcitation and pulse cathode beam excitation, and x-ray photoelectron spectroscopies, and band structure calculations. The differences between the structural, vibrational, luminescence, and electronic properties of the alkali metal-containing [Na2 Ca (VO3) 4 and Na2 Sr (VO3) 4] and the d metal-containing cyclotetravanadates [Ag2 Ca (VO3) 4 and Ag2 Sr (VO3) 4] are analyzed. Na2 Ca (VO3) 4, Ag2 Ca (VO3) 4, Na2 Sr (VO3) 4, and Ag2 Sr (VO3) 4 have tetragonal structures, P4/nbm, with a=10.43849 (6), 10.44524 (5), 10.63449 (4), and 10.62574 (6), and c=4.93873 (5), 4.96845 (5), 4.96205 (4), and 4.97930 (4) Å, respectively. The main structural feature of A2 M (VO3) 4 is the tetracyclic [V4 O12] units. The hybridized O2p-V3d states of the tetracyclic [V4 O12] units have a dominant influence on the electronic structure of these compounds. The compounds are semiconducting with a local density approximation band gap increasing from 1.85 eV for Ag2 Ca (VO3) 4 to 3.02 eV for Na2 Ca (VO3) 4. The prospects of these compounds as advanced materials for detectors of photon and corpuscular radiation as well as for color correction of light emission sources such as lamp and light emitting diode sources are discussed.

AB - The physical properties of the family of cyclotetravanadates A2 M (VO3) 4, where A=Na,Ag and M=Ca,Sr, have been studied by means of x-ray powder diffraction, neutron diffraction, electron diffraction, infrared, Raman, NMR, photoexcitation and pulse cathode beam excitation, and x-ray photoelectron spectroscopies, and band structure calculations. The differences between the structural, vibrational, luminescence, and electronic properties of the alkali metal-containing [Na2 Ca (VO3) 4 and Na2 Sr (VO3) 4] and the d metal-containing cyclotetravanadates [Ag2 Ca (VO3) 4 and Ag2 Sr (VO3) 4] are analyzed. Na2 Ca (VO3) 4, Ag2 Ca (VO3) 4, Na2 Sr (VO3) 4, and Ag2 Sr (VO3) 4 have tetragonal structures, P4/nbm, with a=10.43849 (6), 10.44524 (5), 10.63449 (4), and 10.62574 (6), and c=4.93873 (5), 4.96845 (5), 4.96205 (4), and 4.97930 (4) Å, respectively. The main structural feature of A2 M (VO3) 4 is the tetracyclic [V4 O12] units. The hybridized O2p-V3d states of the tetracyclic [V4 O12] units have a dominant influence on the electronic structure of these compounds. The compounds are semiconducting with a local density approximation band gap increasing from 1.85 eV for Ag2 Ca (VO3) 4 to 3.02 eV for Na2 Ca (VO3) 4. The prospects of these compounds as advanced materials for detectors of photon and corpuscular radiation as well as for color correction of light emission sources such as lamp and light emitting diode sources are discussed.

UR - http://www.scopus.com/inward/record.url?scp=44349172351&partnerID=8YFLogxK

U2 - 10.1103/PhysRevB.77.174113

DO - 10.1103/PhysRevB.77.174113

M3 - Article

VL - 77

JO - Physical Review B-Condensed Matter

JF - Physical Review B-Condensed Matter

SN - 1098-0121

IS - 17

M1 - 174113

ER -

ID: 5062857