Research output: Contribution to journal › Article › peer-review
STRUCTURAL FEATURES AND PROPERTIES OF SODIUM-RUBIDIUM ALUMINOBOROSILICATE GLASSES WITH ZIRCONIUM. / Еремяшев, В.Е.; Korinevskaya, G. G. ; Zhivulin, V. E.; Бочаров, Владимир Николаевич.
In: Glass and Ceramics (English translation of Steklo i Keramika), No. 7-8, 12.11.2024.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - STRUCTURAL FEATURES AND PROPERTIES OF SODIUM-RUBIDIUM ALUMINOBOROSILICATE GLASSES WITH ZIRCONIUM
AU - Еремяшев, В.Е.
AU - Korinevskaya, G. G.
AU - Zhivulin, V. E.
AU - Бочаров, Владимир Николаевич
PY - 2024/11/12
Y1 - 2024/11/12
N2 - By means of vibrational spectroscopy, the study examines the structure of matrix materials synthesized through the quenching of sodium-rubidium aluminoborosilicate melts with the addition of zirconium. Zirconium was found to have a significant effect on the ratio of the main structural units and the distribution of modifier cations among them in the glass structure. The obtained results were used to explain changes in the glass-melt transition temperature and synthesized material density; they can be useful in adjusting the composition and synthesis parameters of matrix materials for the immobilization of high-level radioactive waste containing significant amounts of zirconium.
AB - By means of vibrational spectroscopy, the study examines the structure of matrix materials synthesized through the quenching of sodium-rubidium aluminoborosilicate melts with the addition of zirconium. Zirconium was found to have a significant effect on the ratio of the main structural units and the distribution of modifier cations among them in the glass structure. The obtained results were used to explain changes in the glass-melt transition temperature and synthesized material density; they can be useful in adjusting the composition and synthesis parameters of matrix materials for the immobilization of high-level radioactive waste containing significant amounts of zirconium.
KW - aluminoborosilicate glass
KW - spectroscopy
KW - Vitrification
KW - thermal properties
KW - vitrification
KW - zirconium
KW - radioactive waste
KW - structure
UR - https://www.mendeley.com/catalogue/b3cb03c0-889d-3429-bb5d-4b0e30a941f3/
U2 - 10.1007/s10717-024-00703-z
DO - 10.1007/s10717-024-00703-z
M3 - Article
JO - Glass and Ceramics (English translation of Steklo i Keramika)
JF - Glass and Ceramics (English translation of Steklo i Keramika)
SN - 0361-7610
IS - 7-8
ER -
ID: 127127975