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STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE. / Ertl, A.; Vereshchagin, O.S.; Giester, G.; Tillmanns, E.; Meyer, H.-P.; Ludwig, T.; Rozhdestvenskaya, I.V.; Frank-Kamenetskaya, O.V.

In: Canadian Mineralogist, Vol. 53, No. 2, 2015, p. 209-220.

Research output: Contribution to journal › Article › peer-review

Harvard

Ertl, A, Vereshchagin, OS, Giester, G, Tillmanns, E, Meyer, H-P, Ludwig, T, Rozhdestvenskaya, IV & Frank-Kamenetskaya, OV 2015, 'STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE', Canadian Mineralogist, vol. 53, no. 2, pp. 209-220. https://doi.org/10.3749/canmin.1400078

APA

Ertl, A., Vereshchagin, O. S., Giester, G., Tillmanns, E., Meyer, H-P., Ludwig, T., Rozhdestvenskaya, I. V., & Frank-Kamenetskaya, O. V. (2015). STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE. Canadian Mineralogist, 53(2), 209-220. https://doi.org/10.3749/canmin.1400078

Vancouver

Ertl A, Vereshchagin OS, Giester G, Tillmanns E, Meyer H-P, Ludwig T et al. STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE. Canadian Mineralogist. 2015;53(2):209-220. https://doi.org/10.3749/canmin.1400078

Author

Ertl, A. ; Vereshchagin, O.S. ; Giester, G. ; Tillmanns, E. ; Meyer, H.-P. ; Ludwig, T. ; Rozhdestvenskaya, I.V. ; Frank-Kamenetskaya, O.V. / STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE. In: Canadian Mineralogist. 2015 ; Vol. 53, No. 2. pp. 209-220.

BibTeX

@article{16c0211aa5e7495091047c99676d8fa6,
title = "STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE",
abstract = "A synthetic Cu-rich tourmaline crystal (Lebedev et al. 1988) consists of three different zones. Each zone was characterized by EMPA, SIMS, and single-crystal structure refinement (SREF). The first zone (which crystallized directly on the seed crystal) has the formula ~X(Na0.8□0.2) Y(Al2.0Cu0.9□0.1) ZAl6 T(Si5.1Al0.9)O18 (BO3)3 V(OH)3 W[O0.7F0.2(OH)0.1] with lattice parameters a 15.835(1), c 7.093(1) {\AA} (R = 2.4%). The second zone has the formula ~X(Na0.8□0.2) Y(Al1.8Cu1.1□0.1) ZAl6 T(Si5.1Al0.7B0.2)O18 (BO3)3 V(OH)3 W[(OH)0.4F0.3O0.3] with a 15.824(1), c 7.087(1) {\AA} (R = 2.3%). The third zone (highest Cu content with ~14 wt.% CuO) has the formula X(Na0.81□0.19) Y(Cu1.72Al1.21□0.07) Z(Al5.96Cu0.04) (BO3)3 T(Si5.17Al0.48B0.35)O18 V(OH)3 W[(OH)0.63F0.37] with a 15.849(1), c 7.087(1) {\AA} (R = 2.5%). While [4]Al decreases from zone 1 to zone 3, [4]B increases (by chemistry and SREF), which could be explained by a decreasing temperature during tourmaline crystallization. Such a T-site occupancy is in agreement with the",
keywords = "tourmaline, crystal structure, synthesis, chemistry, copper, Jahn-Teller effect.",
author = "A. Ertl and O.S. Vereshchagin and G. Giester and E. Tillmanns and H.-P. Meyer and T. Ludwig and I.V. Rozhdestvenskaya and O.V. Frank-Kamenetskaya",
year = "2015",
doi = "10.3749/canmin.1400078",
language = "English",
volume = "53",
pages = "209--220",
journal = "Canadian Mineralogist",
issn = "0008-4476",
publisher = "Mineralogical Association of Canada",
number = "2",

}

RIS

TY - JOUR

T1 - STRUCTURAL AND CHEMICAL INVESTIGATION OF A ZONED SYNTHETIC Cu-RICH TOURMALINE

AU - Ertl, A.

AU - Vereshchagin, O.S.

AU - Giester, G.

AU - Tillmanns, E.

AU - Meyer, H.-P.

AU - Ludwig, T.

AU - Rozhdestvenskaya, I.V.

AU - Frank-Kamenetskaya, O.V.

PY - 2015

Y1 - 2015

N2 - A synthetic Cu-rich tourmaline crystal (Lebedev et al. 1988) consists of three different zones. Each zone was characterized by EMPA, SIMS, and single-crystal structure refinement (SREF). The first zone (which crystallized directly on the seed crystal) has the formula ~X(Na0.8□0.2) Y(Al2.0Cu0.9□0.1) ZAl6 T(Si5.1Al0.9)O18 (BO3)3 V(OH)3 W[O0.7F0.2(OH)0.1] with lattice parameters a 15.835(1), c 7.093(1) Å (R = 2.4%). The second zone has the formula ~X(Na0.8□0.2) Y(Al1.8Cu1.1□0.1) ZAl6 T(Si5.1Al0.7B0.2)O18 (BO3)3 V(OH)3 W[(OH)0.4F0.3O0.3] with a 15.824(1), c 7.087(1) Å (R = 2.3%). The third zone (highest Cu content with ~14 wt.% CuO) has the formula X(Na0.81□0.19) Y(Cu1.72Al1.21□0.07) Z(Al5.96Cu0.04) (BO3)3 T(Si5.17Al0.48B0.35)O18 V(OH)3 W[(OH)0.63F0.37] with a 15.849(1), c 7.087(1) Å (R = 2.5%). While [4]Al decreases from zone 1 to zone 3, [4]B increases (by chemistry and SREF), which could be explained by a decreasing temperature during tourmaline crystallization. Such a T-site occupancy is in agreement with the

AB - A synthetic Cu-rich tourmaline crystal (Lebedev et al. 1988) consists of three different zones. Each zone was characterized by EMPA, SIMS, and single-crystal structure refinement (SREF). The first zone (which crystallized directly on the seed crystal) has the formula ~X(Na0.8□0.2) Y(Al2.0Cu0.9□0.1) ZAl6 T(Si5.1Al0.9)O18 (BO3)3 V(OH)3 W[O0.7F0.2(OH)0.1] with lattice parameters a 15.835(1), c 7.093(1) Å (R = 2.4%). The second zone has the formula ~X(Na0.8□0.2) Y(Al1.8Cu1.1□0.1) ZAl6 T(Si5.1Al0.7B0.2)O18 (BO3)3 V(OH)3 W[(OH)0.4F0.3O0.3] with a 15.824(1), c 7.087(1) Å (R = 2.3%). The third zone (highest Cu content with ~14 wt.% CuO) has the formula X(Na0.81□0.19) Y(Cu1.72Al1.21□0.07) Z(Al5.96Cu0.04) (BO3)3 T(Si5.17Al0.48B0.35)O18 V(OH)3 W[(OH)0.63F0.37] with a 15.849(1), c 7.087(1) Å (R = 2.5%). While [4]Al decreases from zone 1 to zone 3, [4]B increases (by chemistry and SREF), which could be explained by a decreasing temperature during tourmaline crystallization. Such a T-site occupancy is in agreement with the

KW - tourmaline

KW - crystal structure

KW - synthesis

KW - chemistry

KW - copper

KW - Jahn-Teller effect.

U2 - 10.3749/canmin.1400078

DO - 10.3749/canmin.1400078

M3 - Article

VL - 53

SP - 209

EP - 220

JO - Canadian Mineralogist

JF - Canadian Mineralogist

SN - 0008-4476

IS - 2

ER -

ID: 3969103