DOI

The estimation of interaction between bodies separated by a slit is a classical problem of surface science, whose solution lays a foundation for the theory of stability of colloidal systems. For dispersion forces without retardation, the pair potential of molecular interaction φij(R) asymptotically is φij(R) = -AijR-6, where Aij is the interaction constant and R is a distance between interacting molecules of sorts i and j. According to the symmetry of a finite slit, there are four nonzero components of the stress tensor, namely, E xx, Eyy, Ezz, and Exz, if x, y, and z are Cartesian coordinates with the z-axis directed normally and the other axes along the slit. Naturally, the existence of force f(x) induces internal stresses and strains in a solid at the slit edge.

Original languageEnglish
Article number106101
JournalJournal of Chemical Physics
Volume131
Issue number10
DOIs
StatePublished - 2009

    Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

ID: 95700138