Starch acetate and carboxymethyl starch as green and sustainable polymer electrolytes for high performance lithium ion batteries

Standard

Starch acetate and carboxymethyl starch as green and sustainable polymer electrolytes for high performance lithium ion batteries. / Hadad, Saeed; Hamrahjoo, Mahtab; Dehghani, Elham; Salami-Kalajahi, Mehdi; Eliseeva, Svetlana N.; Moghaddam, Amir Rezvani; Roghani-Mamaqani, Hossein.

In: Applied Energy, Vol. 324, 119767, 15.10.2022.

Research output: Contribution to journal › Article › peer-review

Author

Hadad, Saeed ; Hamrahjoo, Mahtab ; Dehghani, Elham ; Salami-Kalajahi, Mehdi ; Eliseeva, Svetlana N. ; Moghaddam, Amir Rezvani ; Roghani-Mamaqani, Hossein. / Starch acetate and carboxymethyl starch as green and sustainable polymer electrolytes for high performance lithium ion batteries. In: Applied Energy. 2022 ; Vol. 324.

BibTeX

@article{f96863bdd37b4b2e98f74fbacaa1bd2b,

title = "Starch acetate and carboxymethyl starch as green and sustainable polymer electrolytes for high performance lithium ion batteries",

abstract = "Starch-based electrolytes are used here to achieve safe, efficient, inexpensive, and eco-friendly lithium ion batteries (LIBs). Carboxymethyl starch (CMS) and starch acetate (SA) are synthesized as starch amorphous derivatives from corn starch, and then crosslinked by poly(vinyl alcohol) (PVA) to form a polymer network. In the following, the electrochemical properties of the obtained electrolytes in both solid and gel states are investigated. At room temperature, the ionic conductivity for solid CMS and gel SA electrolytes are 9.2*10-3 S cm−1 and 1.13*10-2 S cm−1, respectively. Other remarkable results of these electrolytes are the wide electrochemical stability window, stable cyclic performance, charge capacity higher than 210 mAh/g, CE = 100 % before 10 cycles charge–discharge for both CMS and SA, and good electrode/electrolyte compatibility. The unparalleled electrochemical performance of CMS and SA, along with their unique properties, make them a unique alternative to liquid electrolytes in LIB.",

keywords = "Gel polymer electrolyte, High ionic conductivity, Lithium ion battery, Solid polymer electrolyte, Starch",

author = "Saeed Hadad and Mahtab Hamrahjoo and Elham Dehghani and Mehdi Salami-Kalajahi and Eliseeva, {Svetlana N.} and Moghaddam, {Amir Rezvani} and Hossein Roghani-Mamaqani",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

year = "2022",

month = oct,

day = "15",

doi = "10.1016/j.apenergy.2022.119767",

language = "English",

volume = "324",

journal = "Applied Energy",

issn = "0306-2619",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Starch acetate and carboxymethyl starch as green and sustainable polymer electrolytes for high performance lithium ion batteries

AU - Hadad, Saeed

AU - Hamrahjoo, Mahtab

AU - Dehghani, Elham

AU - Salami-Kalajahi, Mehdi

AU - Eliseeva, Svetlana N.

AU - Moghaddam, Amir Rezvani

AU - Roghani-Mamaqani, Hossein

PY - 2022/10/15

Y1 - 2022/10/15

N2 - Starch-based electrolytes are used here to achieve safe, efficient, inexpensive, and eco-friendly lithium ion batteries (LIBs). Carboxymethyl starch (CMS) and starch acetate (SA) are synthesized as starch amorphous derivatives from corn starch, and then crosslinked by poly(vinyl alcohol) (PVA) to form a polymer network. In the following, the electrochemical properties of the obtained electrolytes in both solid and gel states are investigated. At room temperature, the ionic conductivity for solid CMS and gel SA electrolytes are 9.2*10-3 S cm−1 and 1.13*10-2 S cm−1, respectively. Other remarkable results of these electrolytes are the wide electrochemical stability window, stable cyclic performance, charge capacity higher than 210 mAh/g, CE = 100 % before 10 cycles charge–discharge for both CMS and SA, and good electrode/electrolyte compatibility. The unparalleled electrochemical performance of CMS and SA, along with their unique properties, make them a unique alternative to liquid electrolytes in LIB.

AB - Starch-based electrolytes are used here to achieve safe, efficient, inexpensive, and eco-friendly lithium ion batteries (LIBs). Carboxymethyl starch (CMS) and starch acetate (SA) are synthesized as starch amorphous derivatives from corn starch, and then crosslinked by poly(vinyl alcohol) (PVA) to form a polymer network. In the following, the electrochemical properties of the obtained electrolytes in both solid and gel states are investigated. At room temperature, the ionic conductivity for solid CMS and gel SA electrolytes are 9.2*10-3 S cm−1 and 1.13*10-2 S cm−1, respectively. Other remarkable results of these electrolytes are the wide electrochemical stability window, stable cyclic performance, charge capacity higher than 210 mAh/g, CE = 100 % before 10 cycles charge–discharge for both CMS and SA, and good electrode/electrolyte compatibility. The unparalleled electrochemical performance of CMS and SA, along with their unique properties, make them a unique alternative to liquid electrolytes in LIB.

KW - Gel polymer electrolyte

KW - High ionic conductivity

KW - Lithium ion battery

KW - Solid polymer electrolyte

KW - Starch

UR - http://www.scopus.com/inward/record.url?scp=85135404580&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/afa34d60-8a5e-3ab3-a26f-62c4be72b3e3/

U2 - 10.1016/j.apenergy.2022.119767

DO - 10.1016/j.apenergy.2022.119767

M3 - Article

AN - SCOPUS:85135404580

VL - 324

JO - Applied Energy

JF - Applied Energy

SN - 0306-2619

M1 - 119767

ER -

ID: 100016580