Research output: Contribution to journal › Article › peer-review
Standard formation enthalpies of gas phase molecular complexes derived by taking into account the heat capacity difference of the gas phase dissociation processes: Experimental tensimetry data revisited. / Davydova, E.I.; Kondrat’ev, Yu.V.; Lisovenko, A.S.; Pomogaeva, A.V.; Sevastianova, T.N.; Timoshkin, A.Y.
In: Thermochimica Acta, Vol. 686, 178571, 04.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Standard formation enthalpies of gas phase molecular complexes derived by taking into account the heat capacity difference of the gas phase dissociation processes: Experimental tensimetry data revisited
AU - Davydova, E.I.
AU - Kondrat’ev, Yu.V.
AU - Lisovenko, A.S.
AU - Pomogaeva, A.V.
AU - Sevastianova, T.N.
AU - Timoshkin, A.Y.
N1 - Publisher Copyright: © 2020 Elsevier B.V.
PY - 2020/4
Y1 - 2020/4
N2 - High temperature tensimetry data on homogeneous gas phase dissociation of donor-acceptor complexes of group 13–15 metal halides have been analyzed. Thermodynamic characteristics and heat capacities have been computed by DFT methods. Standard dissociation enthalpies and standard formation enthalpies of gaseous donor-acceptor complexes have been obtained by combination of experimental and computational data with accounting for the heat capacity change.
AB - High temperature tensimetry data on homogeneous gas phase dissociation of donor-acceptor complexes of group 13–15 metal halides have been analyzed. Thermodynamic characteristics and heat capacities have been computed by DFT methods. Standard dissociation enthalpies and standard formation enthalpies of gaseous donor-acceptor complexes have been obtained by combination of experimental and computational data with accounting for the heat capacity change.
KW - molecular complexes
KW - Gaseous metal halides
KW - thermodynamics
KW - Heat capacity
KW - tensimetry
KW - DFT
KW - Thermodynamics
KW - Tensimetry
KW - Molecular complexes
UR - https://www.sciencedirect.com/science/article/pii/S0040603119309700
UR - http://www.scopus.com/inward/record.url?scp=85080150524&partnerID=8YFLogxK
U2 - 10.1016/j.tca.2020.178571
DO - 10.1016/j.tca.2020.178571
M3 - Article
VL - 686
JO - Thermochimica Acta
JF - Thermochimica Acta
SN - 0040-6031
M1 - 178571
ER -
ID: 51923997